Cement
The cement employed in this investigation was of the grade OPC 53. The amount required to carry out testing was calculated based on the code requirements and acquired as needed. Table 1 shows the tests used to analyse the qualities of cement, which include the specific gravity test (IS: 1727-1967), the test for normal consistency (IS: 5513-1976), the cement setting time test (IS: 4031 (Part 5) -1988), and the fineness of cement.
S.no
|
Property
|
Test values
|
Standard values
|
1
|
Fineness of cement
|
4.12%
|
<10%
|
2
|
Specific gravity
|
3.15
|
-
|
3
|
Consistency
|
30.5%
|
-
|
4
|
Initial setting time
|
49.5 min
|
>30min
|
5
|
Final setting time
|
210min
|
<600min
|
Table 1 Cement physical properties
Fine Aggregate
IS 383-1970 sand can be used in self-compacting concrete. Sand particles less than 0.125mm are considered powder content in the SCC mix in this sand. Sand that has been crushed as well as sand that has been rounded can be used. You can use either siliceous or calcareous sand. The fine material for this project comes from a nearby river stream. It was sieved through a variety of sieves of different diameters in accordance with IS: 383-1970 (2.36mm, 1.18mm, 600, 300, and 150), and the results are displayed in Table 2. Table 3 specifies the parameters of fine aggregates.
Sieve Size
|
% passing recommended by IS -383
|
Weight Retained
(grams)
|
Cumulative weight retained
|
Cumulative % weight retained
|
Cumulative % weight passing through
|
10 mm
|
100
|
0
|
0
|
0
|
0
|
4.75 mm
|
90-100
|
0
|
0
|
0
|
0
|
2.36 mm
|
85-100
|
130
|
130
|
13
|
87
|
1.18 mm
|
75-100
|
110
|
240
|
24
|
76
|
600 micron
|
60-79
|
140
|
380
|
38
|
62
|
300 micron
|
12-40
|
300
|
800
|
80
|
20
|
150 micron
|
0-10
|
200
|
1000
|
100
|
0
|
Table 2 Sieve Analysis of Fine Aggregate
S. no
|
Property
|
Experimental values
|
1
|
Specific gravity
|
2.7
|
2
|
Fineness modulus
|
2.55
|
3
|
Bulk density (loose)
|
15.2KN/m3
|
4
|
Bulk density(dense)
|
16.8KN/m3
|
5
|
Grading
|
Zone-Ш
|
Table 3 Fine Aggregate Physical Properties
Course Aggregate
The coarse aggregate employed in this work (Fig. 1) is crushed granite with a particle size of 10mm, as defined by IS 383-1970, and the experiments that follow were carried out to determine the characteristics of coarse aggregate as defined by IS 2386-1963. (part-III). Table 4 displays the physical properties of coarse aggregate.
S.no
|
Property
|
Experimental Value
|
1
|
Specific gravity
|
2.75
|
2
|
Fineness modulus
|
7.26
|
3
|
Bulk density(loose)
|
15.26KN/m3
|
4
|
Bulk density(dense)
|
16.2KN/m3
|
5
|
Water absorption
|
0.4%
|
Table 4 Coarse Aggregate physical properties.
Water
Portable water is utilised in the concrete preparation and casting processes. When mixed with cement, fine aggregate, and coarse aggregate, it undergoes a hydration process and gradually builds strength.
Copper Slag
Figure 2 shows copper slag, a siliceous by-product of sterile industries that does not leech when exposed to the environment. Because of its glassy structure and toughness, it has attributes similar to genuine river sand. Table 5 shows the properties of copper slag, while Table 6 shows the chemical makeup.
Property
|
Experimental value
|
Color
|
Black, glassy
|
Grain shape
|
Angular
|
Specific gravity
|
3.5
|
Bulk density
|
1750kg/m3
|
Fineness modulus
|
4.55
|
Table 5 Copper slag properties
Chemical composition
|
Content (%)
|
Silica
|
35.12
|
Free silica
|
0.31
|
(Al2O3)
|
2.99
|
Titanium(TiO2)
|
0.39
|
Iron(Fe2O3)
|
57.64
|
Calcium (CaO)
|
0.23
|
Magnesium (MgO)
|
0.92
|
Sodium(Na2O)
|
0.95
|
Potassium(K2O)
|
1.03
|
Copper(Cu)
|
0.31
|
Table 6 Chemical composition of Copper slag
Source: Jawahar,144B, Polepettai, West Tuticorin.
Fly ash
Type C fly ash is employed. Fly ash formed from the combustion of lignite or sub-bituminous coal has certain self-cementing capabilities in addition to pozzolanic properties. The addition of water strengthens class C fly ash, making it more difficult to fly as it ages. Class C fly ash typically has a lime content of 20%. Unlike class F fly ash, self-cementing class C fly ash does not require an activator. Class C fly ash has more alkali and sulphate. Table 7 shows the properties of fly ash, while Table 8 shows the chemical makeup.
Fig. 3 Class C Flyash
Property
|
Experimental value
|
Specific gravity
|
2.2
|
Fineness modulus
|
4.4kg/m2
|
Table 7 Fly ash properties
Chemical Composition
|
Content (%)
|
Silica(SiO2)
|
39.90
|
Alumina.
|
16.70
|
Iron
|
5.80
|
Calcium
|
24.30
|
Magnesium.
|
4.60
|
Sodium(Na2O) and Potassium(K2O)
|
1.30
|
SO3
|
3.30
|
Table 8 Fly ash Chemical composition
Chemical Admixture
In this study, Conplast SP430 (Fig. 4, 5) was used. It's employed when a high amount of workability and retention is essential, such as when there be be delays in installation or when high temperatures will cause quick slump loss. It makes it easier to produce high-quality concrete. Conplast SP430, as a high-range water-reducing admixture, meets IS:9103:1999, BS:5075 Part 3, and ASTM-C-494 Types "F" and "G" at high dosage. "Conplast SP430" appears as a dark liquid that dissolves readily in water. Conplast SP430 was specifically intended to save up to 25% on water without affecting workability or the ability to make high-quality, low-permeability concrete.
Properties of SP 430
- Specific gravity ranges from 120 to 1.22 at 300°C.
- Chloride content - Nil (As per IS: 9103-1999 and BS: 5075)
- Air entrainment - 1% (Approximately.)
- Compatibility: With the exception of high alumina cement, it can be used with any type of cement. When added individually to the mix, Conplast SP430 is compatible with different types of Fosroc admixtures. To optimize doses, number of site trials must be conducted.
- Workability: It can be used to make dynamic concrete that doesn't need to be compacted. To achieve a high working mix without segregation, several modest changes may be required.
- Cohesion: Cement particle dispersion enhances cohesiveness, reduces segregation, and improves surface quality.
- Compressive strength: Conplast SP430 is primarily made up of highly effective super plasticizers that increase workability while retaining compressive strength. Conplast SP430 can be used to produce large water reduction as well as significant compressive strength enhancement.
- Durability: Lowering the W/C ratio allows for increased density and impermeability, which increases the durability of concrete.
Advantages
- It increases workability. Fast placing and compaction.
- Strength increases: If water is reduced in precast concrete, it provides great early strength. It has the advantage of being more durable.
- Risk of segregation and bleeding. reduced
- Free from chloride content, this is safe in pre-stressed concrete and with sulphate-resisting cement.
- It reduces porosity, thereby producing good quality concrete with a denser, close-textured surface.
Dosage and applications
- The best technique to discover the appropriate dose for a concrete mix is to undertake a series of Site trials that track the impacts of workability, strength gain, and cement reduction.
- Conplast SP430 site testing must always be compared to an admixture-free concrete mix.
- As a general rule, the dosage should be between 0.6 and 1.5 litres per 100 kg of cement. If there are any dose differences in specific applications, one has to contact Fosroc Technical Services.
Auramix 200
Auramix 200 (Fig. 6, 7) is a high-performance superplasticizer that sometimes acts as a viscosity modifier that can be used in both low and high-grade concrete and is designed for applications that require significant water reduction and longer workability retention. Auramix 200 was developed for use in concrete with long workability retention and pumpable concrete. Auramix 200 is a unique combination of a new generation super plasticizer and a polycarboxylic ether polymer with a long lateral chain. The electrostatic dispersion mechanism significantly reduces the water demand in flowable concrete. It's a light brown liquid that quickly dissolves in water. Auramix 200 effectively disperses cement particles in the concrete mix, allowing the hydration process to reach a larger surface area. This effect can be used to strengthen concrete, make it more workable, or lower the cement content.
Advantages
Pumping concrete of various grades to greater heights with a low viscosity admixture. A great option is concrete with cement replacements and a low water cement ratio.
- Increases strength without compromising workability or cement content.
- It's perfect for precast concrete.
- The use of a super plasticizer improves workability.
- A lower water-cement ratio means less cracking due to shrinkage.
- Makes the concrete water-resistant.
- Increased resistance to carbonation.
- Mitigate Shrinkage and Creep
- Increased Durability
Properties
- Appearance : Ligh tBrown liquid
- pH: Minimum 6.0
- Volumetricmass@250°C:1.07±0.02kg/liter
- Chloride content: Nil as per BS 5075
Dosage
To determine the appropriate dosage of Auramix 200 to meet a specific requirement, laboratory and batch studies should always be used. In contrast, normal dosage ranges between 0.3 and 1.5 percent by weight of total cement or binder content. Dosage above limits is utilised in consultation with the Berger Fosroc technical department to achieve specific blend criteria. Overdosing can cause delays in setting and segregation. When stored between 20oC and 500oC, Auramix 200 has a minimum shelf life of one year.
Mix Design
In self-compacting concrete, there is no standard process for determining mix proportions. On the other hand, EFNARC requirements include a number of proportional constraints. The mix design is first carried out in compliance with IS 10262–2019, and the quantities of each material are then established by confirming the EFNARC-specifications.
Design
- Grade of concrete = M30
- Cement grade = 53 Grade
- Maximum size of coarse aggregate = 10mm
- Specific gravity of coarse aggregate = 2.75
- Specific gravity of copper slag = 3.5
- Specific gravity of fly ash = 2.2
- Specific gravity of fine aggregate = 2.7
- Fine aggregate zone = Zone Ш
- Specific gravity of cement = 3.15
Procedure
Step-1: Determination of Target mean strength (fck׳)
f'ck = fck+1.65*S (or) fck+X
S= Standard deviation from Table 1 IS10262- 2019 (S=5)
fck = 38.25MPa
fck = characteristic compressive strength at 28 days
Step-2 Selection of water/cement ratio
W/C = 0.4 (after many trails)
Step-3: Selection of maximum water content
From table-2 IS 10262-2019
Water content = 208 lit
Step-4: Required water content = 200 lit/m3 (as per EFNARC7.2)
Step-5: Cement content=500 kg/m3
Step-6: Air entrapped - 1%
From table 3 of IS 10262-2019, amount of air entrapped is 1% of total volume for 10mm size of aggregate
Step-7: From table-3 IS 10262-2019
Depending upon zone of fine aggregate, select the volumes of fine and coarse aggregate
Volume of coarse aggregate = 0.48
Volume of fine aggregate = 0.5
Step-8: Mix Calculation
Volume of concrete=1m3
Volume of cement =0.159 m3
Volume of water = 0.2 m3
Volume of total aggregate (e) = 0.641-superplasticizer
1-0.159-0.2 = 0.641m3
Mass of fine aggregate = e x Volume of fine aggregate x Specific gravity of fine aggregate
=0.635Mass of fine aggregate = 891.54kg/m3
Mass of coarse aggregate = e x Volume of fine aggregate x Specific gravity of Coarse aggregate Mass of coarse aggregate = 821.1kg/m3
Step-10: selection of super plasticizer and viscosity modifying agent
SP dosage = 0.8% of powder content
VMA dosage = 0.2% of powder content
Therefore, the Mix proportion obtained is
Cement: F.A: C.A = 1: 1.78: 1.676
Proportion for SCC Mix (Per 1m3)
Material
|
Nominal Mix
|
20% Copper Slag
|
40% Copper Slag
|
60% Copper Slag
|
80% Copper Slag (Kg)
|
Cement (Kg)
|
415
|
415
|
415
|
415
|
415
|
Fly Ash (Kg)
|
100
|
100
|
100
|
100
|
100
|
Copper Slag(Kg)
|
-
|
186.2
|
372.4
|
558.6
|
744.8
|
Water (lit)
|
190
|
190
|
190
|
190
|
190
|
FA (Kg)
|
931
|
744.8
|
558.6
|
372.4
|
186.2
|
CA (Kg)
|
818
|
818
|
818
|
818
|
818
|
SP (lit)
|
4.1
|
4.1
|
4.1
|
4.1
|
4.1
|
VMA (lit)
|
1.03
|
1.03
|
1.03
|
1.03
|
1.03
|
Table 9 Proportion for SCC mix
Mix Notations
- CS-0: Nominal SCC mix with 20% fly ash
- CS-20: 20% Copper Slag with 20% fly ash
- CS-40: 40% Copper Slag with 20% fly ash
- CS-60: 60% Copper Slag with 20% fly ash
- CS-80: 80% Copper Slag with 20% fly ash