A fluorometric sensor based on poly (β- cyclodextrin/chitosan) with H bonded S QDs/CTSCD nanocomposites was synthesized by self-assembly. They were characterized by FTIR, UV–Vis spectroscopy, XPS, and TEM. The S QDs on the chain of the polymer could coordinate with transition-metal ions due to surface electronegativity. The distance between the S QDs on the different chains of polymer could construct the bridge bond of S–Ag+–S with silver ions leading to fluorescence aggregation-caused quenching. The linear range of the method was from 1.0×10-5 -5.5×10−5mol/L. The correlation coefficient was 0.9992 with a detection limit of 66.7 nM. This method could be used to detect silver ions in real samples with excellent sensitivity and selectivity, indicating its potential as a novel sensor.

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Posted 12 Feb, 2021
Received 06 Feb, 2021
Invitations sent on 06 Feb, 2021
On 05 Feb, 2021
On 24 Jan, 2021
Posted 12 Feb, 2021
Received 06 Feb, 2021
Invitations sent on 06 Feb, 2021
On 05 Feb, 2021
On 24 Jan, 2021
A fluorometric sensor based on poly (β- cyclodextrin/chitosan) with H bonded S QDs/CTSCD nanocomposites was synthesized by self-assembly. They were characterized by FTIR, UV–Vis spectroscopy, XPS, and TEM. The S QDs on the chain of the polymer could coordinate with transition-metal ions due to surface electronegativity. The distance between the S QDs on the different chains of polymer could construct the bridge bond of S–Ag+–S with silver ions leading to fluorescence aggregation-caused quenching. The linear range of the method was from 1.0×10-5 -5.5×10−5mol/L. The correlation coefficient was 0.9992 with a detection limit of 66.7 nM. This method could be used to detect silver ions in real samples with excellent sensitivity and selectivity, indicating its potential as a novel sensor.

Figure 1

Figure 2

Figure 3

Figure 4

Figure 5

Figure 6

Figure 7

Figure 8
This is a list of supplementary files associated with this preprint. Click to download.
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