A mathematical analysis is communicated to the thermal radiative and heat absorption effects on 3D MHD Williamson nanoliquid motion via stretching sheet. The convective heat and mass boundary conditions are taken in sheet when liquid is motion. The suitable similarity transformations, non-dimensionless has been utilized for reduce basic governing PDE’s into coupled system of ODE’s, also compute numerical solutions with the help of 4th order R-K-F procedure with shooting technique in MATLAB programming. The various physical parameters analysed numerically on \(f'(\eta )\)(“Velocity profile”),\(\operatorname{Re} _{x}^{{ - 1/2}}N{u_x}\) (“Heat Transfer Rate”) and \(\operatorname{Re} _{x}^{{ - 1/2}}Sh\) (“Mass Transfer Rate”). We noticed that, the \({\operatorname{Re} _x}^{{1/2}}{C_{fx}}\)(“Skin friction coefficient along \({x^*}\)-axis”), \({\operatorname{Re} _x}^{{1/2}}{C_{fy}}\)(“Skin friction coefficient along \({y^*}\)-axis”) and also compared with precious results and present results for various conditions. Finally, in the present result is good invention of the previous results.