Fractional-order complex-variable dynamical network with complex coupling is considered in this paper. The topological structures and system parameters are assumed to be unknown. As we know, the topological structure and system parameters play a key role on the dynamical behavior of complex network. Thus, how to effectively identify them is a critical issue for better studying the network. Through designing proper controllers and updating laws, two corresponding network estimators are constructed. Based on the Lyapunov function method and Gronwall-Bellman integral inequality, the results are analytically derived. Finally, two numerical examples are performed to illustrate the feasibility of the theoretical results.