Stricter regulations on gas emissions have led car manufacturers to explore different vehicle engine options. Currently, to improve performance in the manufacture of cylinder blocks and cylinder heads of high-powered diesel engines, as well as other castings, a certain number of alloying elements are generally added to gray cast iron. Cast iron grade FC300 materials are widely used to manufacture various industrial products. The reasons are good castability, machinability, and abrasion resistance, and its vibration-dampening capacity is much higher than that of light steels [1, 2, 3]. Given this, the mechanical resistance of cast iron, that is, their ability to withstand external stresses without causing them to cause plastic deformations, and consequently their grades, are conditioned to their final structure obtained [4, 5].
Therefore, this property depends on the shape and amount of graphite and the amount of ferrite and/or perlite in the metallic matrix, in which the resistance is increased with higher levels of perlite and the reduction of the interlayer spacing of the perlite. [5, 6, 7].
The usual mechanism for increasing the tensile strength and hardness of gray cast irons is the addition of alloying elements, such as chromium (Cr), molybdenum (Mo), tin (Sn), and copper (Cu). Additional amounts of copper and tin (pearlized elements) promote the refining of the pearlite or reduction of interlayer spacing, which results in increased strength. On the other hand, Chromium and molybdenum act in the formation of carbides, and, like Sn and Cu, Mo can also be used as a perlite refiner [8, 9].
To achieve a minimum tensile strength of 300 MPa, the carbon content is also reduced from 3.2 to 3.0%, which results in smaller graphite lamellae, thus reducing the risk of starting and crack propagation. In this way, a 10 to 20% increase in mechanical properties is achieved from this [10, 11].
The addition of alloying elements depends on the elemental composition and manufacturing method to provide the desired mechanical properties. Therefore, reducing or eliminating Cu use by technical measures without reducing the mechanical properties and processability in mass production will bring some economic and technological benefits [12, 13].
The study on machinability, cutting strategies, and application technology of gray cast iron is today a priority in large companies and research institutions worldwide, becoming an effective guarantee for high-quality products [14].
Gray cast iron has become a popular material among other cast metals, being widely applied in modern industrial production, mainly for its low cost (20 to 40% less than steel), in addition to having a wide variety of mechanical properties achievable, as good castability, machining property convenient and good wear resistance [15, 16]. The microstructure of gray cast iron is characterized by graphite lamellas dispersed in the ferrous matrix. The casting practice can influence the nucleation and growth of graphite flakes so that the size and type improve the desired properties. The quantity and size of graphite, morphology, and distribution of these lamellae are critical in determining the mechanical behavior of gray cast iron [15, 17].
According to Guesser [9], the machinability of gray cast irons increases as you move towards higher strength grades due to the increased abrasiveness with the increase in the amount of perlite in the matrix and due to the decrease in lubricating action and consequent reduction in ease chip breaking with a decrease in the amount of graphite.
Another way to evaluate the machinability of cast iron is by combining the hardness test with an evaluation of microstructure due to some microconstituents that adversely affect machinability (ASM). Thus, it is emphasized that the microstructure plays a crucial role in altering the mechanical properties of any material [18]. Controlling the microstructure, optimizing the process parameters, and adding alloy elements are highly necessary [18, 19]. The main constituent elements of cast iron are mainly carbon, phosphorus,s and silicon, among others. The presence of silicon and phosphorus determines the solubility of carbon in the molten metal [20]
Silicon is one of the essential elements in producing gray cast iron because it is a stabilizing element of graphite. Thus, it promotes graphite development at the site of iron carbides. It is verified from the experience that the Si content of around 3% restricts the formation of iron carbide because no carbon is left in the chemical form [21].
Adding nickel refines the pearlite structure and graphite gray cast iron, improving strength and hardness to balance the differences in thick sections. High hardness, like that of white cast iron bars, produced by adding sodium chloride salt to gray cast iron, is recommended for wear resistance [22, 23].
As for molybdenum, this is a carbide-forming element used to strengthen and harden iron because of the transformation of austenite into fine perlite and bainite, generally added in gray cast iron to refine perlite [24, 25, 26]. Molybdenum is not a promoter of perlite; however, it is usually added as a ferromolybdenum containing 60 to 70% (Mo) [27, 28]. Copper and molybdenum in gray cast iron guarantee greater hardness and tensile strength than the common pearlitic types of gray cast iron [11].
The gray cast irons of FC300 class possess good mechanical properties, where combinations of multiple structures with low silicon content, fine graphite, and perlite make them stronger and increase their resistance [29, 30]. The combination of microstructure with graphite reinforcement and excellent mechanical strength has led the cast iron alloys of the FC300 class to be used in a wide range of industrial applications, such as automotive parts, internal combustion engines, piping systems, and construction parts [31].
However, compared with conventional FC250 and FC300, the class is considered a lower-cut material. The problems encountered during the machining of the FC300 class are caused by changes in the microstructure formation due to the addition of alloying elements [29, 31]. This is an issue to be considered in industrial environments because it becomes difficult to predict the actual tool life and to specify the most suitable cutting conditions for a given cast alloy.
The integrity of the surface is directly related to the quality achieved in the final machining, which strongly affects the product's performance. Among the factors that can influence the quality of the product's surface are the cutting speed, the feed, the depth of cut, the geometry of the tool, the wear of the tool, and the properties of the part [29, 32].
In practice, machining operations can only fully develop the potential of machine tools and cutting tools after optimizing the cutting parameters to obtain the best work efficiency and tool life [33, 34].
The present study aims to evaluate the influence of the microstructure on the machinability of gray high-strength cast iron, of the FC300 class, for use in diesel engine blocks and heads. For this purpose, two versions of FC300 gray cast iron were produced, one with graphite refining (FC 300 (RG)) and the other, which in addition to graphite refining, has molybdenum addition (FC 300 (Mo + RG)). The FC250 gray cast iron and vermicular iron FV450 were also investigated for comparison purposes. These materials were machined in the front milling, with carbide tools, with comparisons of the tool life and the surface roughness of the part, considering in the analysis and discussions of the results the microstructural characteristics of the materials.