Background: The International Maritime Organization (IMO) has set limits on sulphur content in fuels for marine transport. However, vessels continue to use these residual high sulphur fuels in combination with exhaust gas cleaning systems (EGCS or scrubbers). Next to high sulphur, combustion of these fuels also results in higher emissions of contaminants including metals and PAHs. In scrubbers, exhaust gases are sprayed with water in order to remove SOx, resulting in acidic washwater with elevated contaminant concentrations discharged in the aquatic ecosystem. The number of vessels with scrubbers is increasing rapidly, but knowledge on washwater quality and impact are limited.
Results: The scrubber washwater is found to be acidic with elevated concentrations of e.g. zinc, vanadium, copper, nickel, phenanthrene, naphthalene, fluorene and fluoranthene. Model calculations on the effects of scrubber discharge under scenario HIGH (20% of vessels, 90th percentile concentrations) on the water quality in harbor docks showed a decrease in pH of 0.015 units and an increase in surface water concentrations for e.g. naphthalene (189% increase) and vanadium (46% increase).
Conclusions: The IMO established sulphur regulations to mitigate the impact of high sulphur emissions of the maritime sector. However, the use of open loop scrubbers as an abatement technology will not reduce their contribution to ocean acidification. In addition, different types of scrubbers discharge washwater that is acute toxic for aquatic organisms. However, washwater is diluted and the compounds for which a large increase in surface water concentrations was calculated in the Antwerp (Belgium) harbour docks (Naphthalene > Phenanthrene > Fluorene > Acenaphthene > Vanadium) were not the compounds that already exceed their respective Water Quality Standards (WQS). Nevertheless, the WQS of several ‘priority hazardous substances’ (Water Framework Directive) are already exceeded in the docks and the Scheldt estuary. Since these hazardous substances are also identified in the washwater, scrubber washwater discharge should be discouraged in coastal waters and estuaries with large ecological value.

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Posted 15 Jul, 2020
On 10 Jul, 2020
On 10 Jul, 2020
On 09 Jul, 2020
On 09 Jul, 2020
Received 26 May, 2020
On 26 May, 2020
Received 25 May, 2020
Received 20 May, 2020
On 05 May, 2020
On 29 Apr, 2020
On 26 Apr, 2020
Invitations sent on 25 Apr, 2020
On 23 Apr, 2020
On 22 Apr, 2020
On 18 Apr, 2020
On 17 Apr, 2020
Posted 15 Jul, 2020
On 10 Jul, 2020
On 10 Jul, 2020
On 09 Jul, 2020
On 09 Jul, 2020
Received 26 May, 2020
On 26 May, 2020
Received 25 May, 2020
Received 20 May, 2020
On 05 May, 2020
On 29 Apr, 2020
On 26 Apr, 2020
Invitations sent on 25 Apr, 2020
On 23 Apr, 2020
On 22 Apr, 2020
On 18 Apr, 2020
On 17 Apr, 2020
Background: The International Maritime Organization (IMO) has set limits on sulphur content in fuels for marine transport. However, vessels continue to use these residual high sulphur fuels in combination with exhaust gas cleaning systems (EGCS or scrubbers). Next to high sulphur, combustion of these fuels also results in higher emissions of contaminants including metals and PAHs. In scrubbers, exhaust gases are sprayed with water in order to remove SOx, resulting in acidic washwater with elevated contaminant concentrations discharged in the aquatic ecosystem. The number of vessels with scrubbers is increasing rapidly, but knowledge on washwater quality and impact are limited.
Results: The scrubber washwater is found to be acidic with elevated concentrations of e.g. zinc, vanadium, copper, nickel, phenanthrene, naphthalene, fluorene and fluoranthene. Model calculations on the effects of scrubber discharge under scenario HIGH (20% of vessels, 90th percentile concentrations) on the water quality in harbor docks showed a decrease in pH of 0.015 units and an increase in surface water concentrations for e.g. naphthalene (189% increase) and vanadium (46% increase).
Conclusions: The IMO established sulphur regulations to mitigate the impact of high sulphur emissions of the maritime sector. However, the use of open loop scrubbers as an abatement technology will not reduce their contribution to ocean acidification. In addition, different types of scrubbers discharge washwater that is acute toxic for aquatic organisms. However, washwater is diluted and the compounds for which a large increase in surface water concentrations was calculated in the Antwerp (Belgium) harbour docks (Naphthalene > Phenanthrene > Fluorene > Acenaphthene > Vanadium) were not the compounds that already exceed their respective Water Quality Standards (WQS). Nevertheless, the WQS of several ‘priority hazardous substances’ (Water Framework Directive) are already exceeded in the docks and the Scheldt estuary. Since these hazardous substances are also identified in the washwater, scrubber washwater discharge should be discouraged in coastal waters and estuaries with large ecological value.

Figure 1

Figure 2

Figure 3

Figure 4
The full text of this article is available to read as a PDF.
This is a list of supplementary files associated with this preprint. Click to download.
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