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Samples of orange patinas found on a limestone balustrade and an ornament of the Batalha Monastery have been investigated by X-ray micro-diffractometry (µ-XRD) and Low-Vacuum Scanning Electron Microscopy coupled with Energy Dispersive Spectrometry (LV-SEM + EDS). Aim of the study was to determine the composition of the layered patinas, assess whether they were been intentionally applied or naturally formed, and study their degradation patterns. Preliminary results revealed that the orange patinas on the balustrade and the ornament showed different compositions and appearance, suggesting distinct formation pathways. Orange layers on the ornament which suffers salt decay and delamination nowadays, mainly consisted of gypsum with hematite as a minor component, implying the possibility of an intentional application of a mixture of ochre and lime as tint plaster. Orange patinas on the balustrade show the presence of Ca-oxalates, abundant weddellite and minor whewellite, with minor hematite suggesting the yellowish/orange color to be due to Ca-oxalate patinas imbedding soil dust airborne particles. Such patina was possibly formed naturally either by the chemical attack due to atmospheric air pollutants from traffic exhausts emissions or by bacterial activity. No delamination was observed, abrasion is the major decay phenomenon on the balustrade sample. A comparison was made between this patina and the so called “scialbatura”, a surface yellowish coating often found by conservators on limestone and marble in ancient monuments in the Mediterranean region.
Keywords
limestone balustrade, Batalha Monastery, Ca-oxalate patinas imbedding soil dust airborne particles, Mediterranean region
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View the published article at Environmental Science and Pollution Research.
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See the published version of this preprint at Environmental Science and Pollution Research.
This is a preprint, a preliminary version of a manuscript that has not completed peer review at a journal. Research Square does not conduct peer review prior to posting preprints. The posting of a preprint on this server should not be interpreted as an endorsement of its validity or suitability for dissemination as established information or for guiding clinical practice.
Learn more about In Review
Research Article
Badges
Prescreen
This manuscript passed our Prescreen assessment
Complete author information
Appropriate declaration statements
Potential risks to human health
Prescreen
Peer Review Timeline
CURRENT STATUS: Published
View the published article at Environmental Science and Pollution Research.
Version 1
Posted 05 Apr, 2021
No community comments so far
Reviews received
Received 05 Apr, 2021
Reviewers invited
Invitations sent on 29 Mar, 2021
First submitted
On 15 Feb, 2021
Metrics
Comments: 0
PDF Downloads: ...
HTML Views: ...
License:
This work is licensed under a CC BY 4.0 License. Read Full License
View the published article at Environmental Science and Pollution Research.
Samples of orange patinas found on a limestone balustrade and an ornament of the Batalha Monastery have been investigated by X-ray micro-diffractometry (µ-XRD) and Low-Vacuum Scanning Electron Microscopy coupled with Energy Dispersive Spectrometry (LV-SEM + EDS). Aim of the study was to determine the composition of the layered patinas, assess whether they were been intentionally applied or naturally formed, and study their degradation patterns. Preliminary results revealed that the orange patinas on the balustrade and the ornament showed different compositions and appearance, suggesting distinct formation pathways. Orange layers on the ornament which suffers salt decay and delamination nowadays, mainly consisted of gypsum with hematite as a minor component, implying the possibility of an intentional application of a mixture of ochre and lime as tint plaster. Orange patinas on the balustrade show the presence of Ca-oxalates, abundant weddellite and minor whewellite, with minor hematite suggesting the yellowish/orange color to be due to Ca-oxalate patinas imbedding soil dust airborne particles. Such patina was possibly formed naturally either by the chemical attack due to atmospheric air pollutants from traffic exhausts emissions or by bacterial activity. No delamination was observed, abrasion is the major decay phenomenon on the balustrade sample. A comparison was made between this patina and the so called “scialbatura”, a surface yellowish coating often found by conservators on limestone and marble in ancient monuments in the Mediterranean region.
Figure 1
Figure 2
Figure 3
Figure 4
Figure 5
Figure 6
Figure 7
Figure 8
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