Effects of different soil amendments on the physical and chemical properties of saline-alkali soil
Change of soil salt content
Soil salt content is an important indicator of soil salinization. An extremely high soil salt content will cause damage to plants and hinder the normal growth and development of plants, resulting in poor quality and reduced yield. Figure 1 shows that the application of humic acid can significantly reduce the salt content of the surface layer (0–20 cm) of soil, which is 12.43% lower than that of the control. This phenomenon is mainly due to the high cation exchange capacity of humic acid, which can significantly improve the anion adsorption capacity of soil and reduce the salt content of the surface soil after its application. In addition, humic acid can improve the soil aggregate structure, improve the soil porosity, destroy the salt rising conditions, and play a role in salt removal. The variance analysis results show no significant difference in the salt content of the surface soil with desulfurized gypsum and the “Jinfufeng” soil conditioner compared with the control. The soil salt content of the four treatments showed a distribution pattern of high surface layer (0–20 cm), low middle layer (20–40 cm), and high bottom layer (40–60 cm). The salt content of the 0–20 and 20–40 cm soil layers in the test area before rice planting was 2.97 and 2.10 g • kg-1, respectively, and their average salt content after rice planting was 1.78 and 1.61 g • kg-1, respectively, indicating that rice planting can significantly reduce the salt content of the soil surface, mainly due to the leaching effect of well water irrigation and the reduction of surface evaporation after rice planting. Moreover, rice has a certain absorption effect on the salt ions in the soil. In addition, rice planting has a significant impact on promoting the formation of soil aggregates and improving the soil structure, which can promote water movement in the soil profile and reduce the occurrence of salt return, significantly reducing the soil salt content after rice planting [16].
Soil pH change
Soil pH is an important indicator of the soil acid-base status, which directly affects the form and availability of nutrient elements in the soil. An extremely high or low soil pH is not conducive to the absorption of nutrient elements by plant roots [17]. The distribution of the soil pH in the 0–60 cm soil layer under different soil amendments is shown in Figure 2. Each treatment shows a distribution pattern of low surface soil pH and high deep soil pH. The pH of the surface soil treated with CK is high, reaching 8.9. According to the classification standard of soil acidity and alkalinity in China, the soil has reached strong alkalinity, which seriously affects the normal growth of rice. The other three soil amendments can significantly reduce the pH of the surface soil. Compared with the control, the pH of the surface soil treated with FGD, SC, and HA decreased by 5.78%, 4.53%, and 5.55% respectively. The pH of the treatment with the “Jinfufeng” soil conditioner is 3.0–4.0, and that of humic acid is 4.7, which are acidic. These treatments can neutralize with the alkali in the soil and reduce the soil pH. The main components of desulfurized gypsum are CaSO4 and a small amount of CaSO3. After adding desulfurized gypsum to the soil, the Ca2+in the gypsum reacted with the free NaHCO3 and Na2CO3 in the soil to generate insoluble CaCO3 or Ca(HCO3)2, which reduced the soil pH.
Change of soil bulk density
Soil bulk density can reflect the soil compactness, which is an important physical property reflecting soil water, fertilizer, air, heat, and other factors. The saline soil bulk density is generally large, with a compact structure and poor permeability. The saline is difficult to improve and use [18-19]. The results in Table 2 show that the application of a soil conditioner can effectively reduce the soil bulk density, increase the soil porosity, and improve the soil physical properties of the 0–40 cm soil layer, and humic acid has the best effect on improving the soil physical properties among the conditioners. Compared with the control, the FGD, SC, and HA treatments significantly reduced the bulk density of the surface soil by 0.04, 0.07, and 0.08 g•cm-3, and that of the middle soil by 0.07, 0.10, and 0.11 g•cm-3, respectively. No significant difference could be observed in the bulk density of the deep soil.
Change of soil bulk density
Soil nutrients are essential nutrients for plants provided by soil, and the important indicators of soil nutrients mainly include soil organic matter, total nitrogen, available phosphorus, and available potassium. The effect of different soil amendments on the soil nutrients in the low-lying saline-alkali soil in Northern Shaanxi is shown in Table 3. Compared with the control treatment, the soil organic matter and total nitrogen contents significantly increased after adding “Jinfufeng” soil amendments and humic acid, and the available potassium content significantly increased after adding desulfurization gypsum. The mechanism is that the “Jinfufeng” soil conditioner and humic acid contain a certain amount of organic matter and nitrogen, so adding them to the soil increases the soil organic matter and total nitrogen contents, but the available phosphorus and available potassium contents are low, so the impact is insignificant. Applying desulfurized gypsum can promote the adsorption of potassium by the soil colloid, thus increasing the exchangeable potassium ions in the soil as well as the available potassium in the soil. Among the treatments, the SC treatment achieved the largest organic matter content at each soil layer depth, with an average value of 10.0 g•kg-1, which is 21.61%, 19.57%, and 3.37% higher than those achieved by the CK, FGD, and HA treatments, respectively, indicating that the “Jinfufeng” soil conditioner has the most significant effect on the increase of the soil organic matter content. The total nitrogen content achieved by the HA treatment is the highest, with an average value of 0.97 g•kg-1, which is 35.14%, 32.08%, and 14.02% higher than those achieved by the CK, FGD, and SC treatments, respectively. The soil available potassium is the highest in the FGD treatment, and the average content is 113mg•kg-1, which is 8.65%, 8.65%, and 9.71% higher than those in the CK, AG, and HA treatments, respectively.
Effects of different soil amendments on rice yield and economic benefits
The 1000-grain weight of rice can reflect the grain size and plumpness of rice and is an important basis for testing the quality of rice and predicting the field yield. Table 4 shows that the application of soil conditioner can improve the 1000-grain weight and yield of rice. Compared with the control, the 1000-grain weight and yield of rice increased by 10.19%–13.59% and 13.54%–27.95%, respectively, after applying soil amendments. Among them, the 1000-grain weight and yield of the HA treatment are the largest, reaching 23.4 g and 7380 kg • hm-2, respectively. In addition, the analysis of the economic benefits revealed that the application of modifiers can improve the output value and net profit of rice. Among the treatments, the HA treatment obtained the largest output value, net profit, and output to investment ration, which are 25830.0 yuan •hm-2, 6564 yuan•hm-2, and 2.31 yuan, respectively. Compared with the FGD and SC treatments, the output to investment ratio of the HA treatment increased by 67.01% and 13.68%, respectively. In comprehensive consideration of the rice quality and yield and the economic benefits, a humic acid soil conditioner should be preferentially selected to improve the low-lying saline-alkali land in this area.