High-strength steel (HSS) welding electrode specifications offer two sets of Tables for compliance, one on Specified Electrode Chemical Composition Requirements and the other on Specified Minimum Weld Mechanical Properties Requirements. These sets of Tables may appear mutually exclusive but underlying metallurgical principles keep them inter-dependent. Suppressing austenite transformation-start (TS) temperature simultaneously increases both strength and low-temperature impact toughness of HSS weld metal (WM). Specifically, a two-step approach is useful in understanding the metallurgy of high-performance electrodes and WMs. This approach includes calculated TS temperatures such as Ar3, BS or MS, besides carbon content, carbon equivalent number (CEN) and balanced Ti (and/or Zr), B, Al, N, O additions that correlate identified WM chemical composition with desired high-performance microstructures to meet or exceed minimum WM tensile and Charpy V-notch (CVN) impact toughness property requirements. The first step uses a set of constitutive (statistical/regression) equations to control the amounts of principal alloy elements such as C, Mn, Cr, Ni, Mo, and Cu so the relevant calculated TS temperatures such as Ar3, BS, or MS and CEN stay in a desirable range relative to the base metals being joined. While doing so, one also needs to ascertain that the common progression of calculated TS temperatures wherein Ar3 > BS > MS remains valid. The second step requires balanced Ti (and/or Zr), B, Al, N, O additions to further lower the actual TS temperature compared to the calculated TS temperature. Both a lower TS temperature and a narrow start-to-finish (TS–TF) temperature range ensure exceptional CVN impact toughness. The balanced Ti (and/or Zr), B, Al, N, O content can be ascertained using an artificial neural network (ANN) model offered by the Japan Welding Engineering Society (JWES) at its website. The JWES ANN model allows one to manipulate 16 elements of the WM compositions, each within a specified range and seek a lower predictive temperature range for achieving 28 J absorbed energy (T28J/°C) during CVN impact testing.