Urea is a commonly used nitrogen fertiliser synthesised from ammonia and carbon dioxide using thermal catalysis. This process results in high CO2 emissions associated with the required amounts of ammonia, Electrocatalysis provides an alternative method to urea production with reduced carbon emissions while utilising waste products like nitrate. This manuscript reports on urea synthesis from the electroreduction of nitrate and carbon dioxide using CuOxZnOy electrodes under mild conditions. Catalysts with different ratios of CuO and ZnO, synthesised via flame spray pyrolysis, were explored for the reaction. The results revealed that all the CuOxZnOy electrocatalyst compositions produce urea, but the efficiency strongly depends on the metal ratio composition of the catalysts. The CuO50ZnO50 composition had the best performance in terms of selectivity (41% at -1.3 V vs Ag/AgCl) and activity (0.27 mA/cm2 at -1.3 V vs Ag/AgCl) towards urea production Thus, this material is within the most efficient electrocatalyst for urea production reported so far. This pioneer study systematically evaluates bimetallic catalysts with varying compositions for urea synthesis from CO2 and nitrate.