3.1.1 Results of the Raw and Treated Samples
Samples were analyzed for physicochemical and bacteriological parameters. Samples were taken before treatment (Raw water) and after treatment with chlorine, alum, and lime (treated water). Results were obtained and further compared with sample from the test well results to ascertain if the recommendation is adequate. All results were compared with the Nigeria Standards for Drinking Water Quality and WHO standards (26) (28).
The results of the assessment of the physical parameters of the raw and treated water samples are presented in Table 2. The physical parameter study yielded interesting findings about the quality of the raw water samples. The range of temperature values (28 – 29oC) were within the permissible ranges specified by both the NSDWQ and the WHO (22 – 30oC). In contrast to the specified standard of a clean and colorless appearance, the ocular assessment showed the presence of color and turbidity in all samples (A-D). Likewise, disagreeable taste and odor were observed in all samples, departing from the recommendations' specified unobjectionable features (Table 2). Turbidity levels in nephelometric turbidity units (NTU) exceeded the NSDWQ's maximum recommended limit. The conductivity levels were higher than the WHO limits, indicating that the water samples had a higher mineral content. Salinity data lacked defined guideline values but revealed excessive levels. Total dissolved solids (TDS) exceeded the maximum recommended amount as well, which is evidence that there is presence of diverse dissolved elements.
The result of the assessment of physical parameters in treated water samples (Table 3) indicated that the recommended standards were satisfied in general. Temperature values were within the permitted ranges specified by both the NSDWQ and the WHO, which is also similar to the raw samples. Visual inspection revealed that most of the samples were clear and colorless, except for Sample C2, which had minor coloring. Color measurements in Hazen units revealed values of 7.5, 9, and 8.5 for A2, B2, and C2, respectively, indicating low color presence. These readings were significantly below the recommendations' maximum limit of 15 Hazen units by the NSDWQ. While disagreeable taste and odor were observed for all samples, these findings could be said to meet the NSDWQ and WHO standards. Turbidity levels in the samples (0 – 3.5 NTU) were within permissible limits (5 NTU), indicating that suspended particles were effectively removed throughout the treatment process. Although conductivity levels were marginally different in some samples (A2 – C2), only D2 did not surpass the WHO's recommended range. There were no guideline values for salinity measurements, however all samples showed levels within safe limits.
The analysis of chemical properties in both raw (raw) and treated water samples as presented in Table 3, also provided valuable insights into the composition and effectiveness of water treatment processes. Several chemical parameters of the raw water samples differ among the samples. The pH values vary between 6.8 to 7.0, indicating conditions that were slightly acidic to neutral. The failure to detect residual chlorine indicates that the raw water samples were not disinfected. The iron contents ranged from 0.5 mg/l to 0.8 mg/l, with sample B having the lowest and Sample D, on the other hand, having the highest. The total alkalinity ranged from 12 mg/l (Sample A) to 97 mg/l (Sample B), while the total hardness ranged from 537 mg/l (Sample B) to 586 mg/l (Sample A). The amounts of chloride varied between 95 mg/l to 117 mg/l, while nitrate levels ranged from 0 mg/l to 1.4 mg/l. No residual aluminum was found within any of the raw water samples.
The chemical parameters of the water samples improved noticeably after treatment (Table 4). The pH levels varied between 6.9 to 7.6, suggesting an increase in alkalinity. Residual chlorine was not found in any of the treated water samples, suggesting either the disinfection was effective or because of initial absence, the treatment system does not cater for chlorine removal. Iron levels dropped drastically, with levels ranging from 0.049 mg/l to 0.27 mg/l. The total alkalinity ranged from 89 to 98 mg/l, while the total hardness ranged from 400 to 442 mg/l. The total chloride concentrations in the treated samples ranged from 102 mg/l to 142 mg/l. Nitrate levels in treated water samples remained low, ranging from 0 mg/l to 1.4 mg/l. Only Sample D2 contained residual aluminum at a value of 0.1 mg/l.
The result of the microbial analysis of the water samples are presented in Table 5. It was found that the aerobic mesophilic were too numerous to count in the raw samples. This exceeds both the WHO and NSDWQ standard which was set to be less than 100 cfu/ml. The total coliform result of all the samples were observed to be greater than the minimum of 0 set by the WHO and NSDWQ (range of 99 – 115 MPN/100ml). In the treated samples (Table 5), it was observed that there was a significant reduction in aerobic mesophilic of sample A (sample A2 = 10 cfu/ml) and lower than the WHO and NSDWQ standards (100 cfu/ml). However, the reduction in other samples (B2-D2) ranged from 124 – 142 cfu/ml which is above the standards of comparison. The total coliforms in all samples reduced effectively to 0 MPN/100 ml in all the treated samples, indicating the effectiveness of the treatment technique.
Table 2: Organoleptic Parameters of Raw (A-D) and Treated Water Sample (A2-D2)
Organoleptic Parameters
|
Sample A
|
Sample B
|
Sample C
|
Sample D
|
Sample A2
|
Sample B2
|
Sample C2
|
Sample D2
|
NSDWQ
|
WHO
|
Visual Inspection
|
Brownish
|
Turbid and Brownish
|
Turbid and Brownish
|
Turbid and Brownish
|
Clear
|
Clear/Colorless
|
Slight coloration
|
Clear
|
Clear/Colorless
|
Clear
|
Color (Hazen)
|
Brownish
|
48
|
53
|
46
|
Colorless
|
7.5
|
9
|
8.5
|
0-15
|
Colorless
|
Taste
|
Objectionable
|
Objectionable
|
Objectionable
|
Objectionable
|
Objectionable
|
Objectionable
|
Objectionable
|
Objectionable
|
Unobjectionable
|
Unobjectionable
|
Odor
|
Objectionable
|
Objectionable
|
Objectionable
|
Objectionable
|
Odorless
|
Unobjectionable
|
Unobjectionable
|
Unobjectionable
|
Unobjectionable
|
Odorless
|
NOTE: WHO: World Health Organization, NSDWQ: Nigeria Standard for Drinking Water Quality.
Table 3: Physical Properties of Raw (A-D), Treated (A2-D2) and Improved Treated (IT) Water Samples
Physical Parameters of Raw Water Sample
|
Physical Parameters of Treated and Improved Treated Water Sample
|
|
Sample A
|
Sample B
|
Sample C
|
Sample D
|
Sample A2
|
Sample B2
|
Sample C2
|
Sample D2
|
IT Sample
|
NSDWQ
|
WHO
|
Temperature of water (◦C)
|
28
|
28
|
29
|
29
|
28
|
28
|
28
|
27
|
28
|
22-30
|
22-30
|
Temperature of Air (◦C)
|
27
|
27
|
27
|
27
|
27
|
27
|
28
|
28
|
27
|
25-30
|
25-30
|
Turbidity (NTU)
|
12.4
|
13.71
|
12.3
|
11.9
|
0
|
2.31
|
3.5
|
3.15
|
2.75
|
5
|
|
Conductivity (µS/cm)
|
1390
|
1362
|
1387
|
1387
|
202
|
1226
|
1274
|
1315
|
434
|
1500
|
900-1200
|
Salinity (mg/L)
|
652
|
681
|
630
|
612
|
612
|
613
|
610
|
622
|
217
|
No guideline values
|
---
|
Total Dissolved Solids (mg/L)
|
746
|
885
|
899
|
884
|
96.4
|
797
|
797
|
753
|
282
|
1200 (Maximum)
|
500
|
Table 4: Chemical Properties of Raw (A-D), Treated (A2-D2) and Improved Treated (IT) Water Samples
|
Chemical Properties of Raw Water Samples
|
Chemical Properties of Treated and Improved Treated Water Samples
|
|
Sample A
|
Sample B
|
Sample C
|
Sample D
|
Sample A2
|
Sample B2
|
Sample C2
|
Sample D2
|
IT Samples
|
NSDWQ
|
WHO
|
pH
|
6.9
|
6.8
|
6.9
|
7
|
7.5
|
7.3
|
6.9
|
7.6
|
7.4
|
6.8-8.5
|
6.8-8.5
|
Residual Cl (mg/L)
|
0
|
0
|
0
|
0
|
0
|
0
|
0
|
0
|
0
|
0.2-0.5
|
0.2
|
Iron (mg/L)
|
0.8
|
0.5
|
0.7
|
0.8
|
0.049
|
0.25
|
0.27
|
0.24
|
0.2
|
0.3
|
0.1-1.0
|
Total Alkalinity (mg/L)
|
12
|
97
|
94
|
94
|
12
|
94
|
98
|
89
|
20
|
No guideline value
|
30-500
|
Total Hardness (CaCO3mg/L)
|
586
|
537
|
584
|
564
|
ND
|
421
|
442
|
426
|
58
|
400
|
30-200
|
Calcium Hardness (CaCO3mg/L)
|
ND
|
372
|
390
|
395
|
ND
|
302
|
310
|
307
|
39
|
200
|
75-200
|
Mg Hardness (CaCO3mg/L)
|
ND
|
165
|
173
|
171
|
ND
|
119
|
111
|
117
|
19
|
50
|
|
Chloride (mg/L)
|
95
|
117
|
108
|
102
|
40
|
102
|
121
|
142
|
13.5
|
250
|
200-600
|
Nitrate (mg/L)
|
1.4
|
0
|
0
|
0
|
1.4
|
0
|
0
|
0
|
0
|
0.1
|
5 to 30
|
Residual Aluminum (mg/L)
|
ND
|
0
|
0
|
0
|
ND
|
0
|
0
|
0.1
|
0
|
0.2
|
|
NOTE: ND: Not Determined, WHO: World Health Organization, NSDWQ: Nigeria Standard for Drinking Water Quality.
Table 5: Microbial Properties of Raw, Treated and Improved Treated Water Samples
Microbiological Parameter s of Raw Water Samples
|
Microbiological Parameters of Treated and Improved Treated Water Samples
|
|
|
|
Sample A
|
Sample B
|
Sample C
|
Sample D
|
Sample A2
|
Sample B2
|
Sample C2
|
Sample D2
|
IT Sample
|
NSDWQ
|
WHO
|
Aerobic Mesophilic (cfu/ml)
|
TNTC
|
TNTC
|
TNTC
|
TNTC
|
10
|
128
|
124
|
142
|
28
|
˂100
|
100
|
Total Coliforms (MPN/100ml)
|
99
|
102
|
115
|
115
|
0
|
0
|
0
|
0
|
0
|
0
|
0
|
NOTE: ND: WHO: World Health Organization, TNTC: Too Numerous to Count, NSDWQ: Nigeria Standard for Drinking Water Quality.
3.1.2 Results of the Improved Treatment System Design
This study also attempted to build a treatment system that can be a better option for treating the water for safe drinking. Water sample was collected from borehole and treated as recommended in the improved treatment method. The treatments employed are Hypochlorite, Soda ash, Alum, media filter tank, activated carbon filter tank and Iron resin filter tank. The filter tanks were separated and increased to three for a more efficient treatment process. Figure 10 showed the common treatment system existing in the study area and figure 11 showed an improved treatment system design. The water quality result was presented in Table 4 and Table 5. The physical parameters such as temperature, visual inspection, color, turbidity, conductivity, salinity, and total dissolved solids, were found to be lower than the standard set by the NSDWQ. Similar lower values and within permissible range were obtained for the chemical and microbial parameters measured.
More comprehensive representations of the data compared with the control standards are further presented in Figures 2 to 9. Figure 2 compares the temperature of all the samples with the improved treatment system. Figure 3 shows the comparison of the turbidity values of all the samples. Figure 4 shows the conductivity values of all the water samples. Figure 5 shows the comparison between the total dissolved solids of all the water samples. Figure 6 represents the pH values of all the water samples. Figure 7 shows the comparison total hardness of all the samples. Figure 8 compares the total alkalinity and Figure 9 compares the values of the concentration of chlorine for all the water samples.
3.2 Discussion
Physical parameter measurement in both raw and treated water samples provide useful information into the efficacy of water treatment methods and their consequences for water quality. A comprehensive comparison of the findings reveals significant findings as well as potential implications for water resource management and public health.
Several metrics in the raw water samples deviated from the NSDWQ and WHO approved levels. Color, disagreeable taste and odor, increased turbidity, conductivity, salinity, and total dissolved solids all specify that there is a need for improvement in the currently existing treatment technology to guarantee compliance with water quality criteria. These findings highlight the need to establish efficient purification techniques to eliminate contaminants and improve the safety and usage of water supplies.
The pH values of less than 7.0 of the raw water samples indicate a slightly acidic condition. Deep groundwater sources like boreholes frequently have low pH levels in their groundwater. Due to the presence of CO2, which is produced in the soil by both aerobic and anaerobic microbial processes, as well as the fact that at such depths it is difficult for it to easily escape into the atmosphere, groundwater has a low pH (29).
The increase in the pH values observed in the treated samples emphasized the significance of pH control water quality management as posited by Li and Wu (2019) (30). Hoko (2008) (29) posited that water taste is influenced by pH, hence, there is a need for adequate treatment for pH in water situated for drinking. Temperature has an impact on nature and degree of other parameters, such as conductivity. The temperature also influences bacterial activity. Warm temperatures lead to accelerated bacterial activity, which increases the potential for the development of odors through the oxygen-depleting oxidation of organic and nitrous compounds that may be present in water (29).
Furthermore, the lack of residual chlorine in raw water samples emphasizes the importance of good disinfection during treatment, as chlorine is a critical agent for pathogen elimination (31). The turbidity values of the samples in the present study were found to be lower than the report of Palamuleni and Akoth (2015) (5) study carried out in South Africa where a maximum of 40.9 NTU was discovered. The result revealed a high level of turbidity in the raw water samples. The dissolved solids, high organic matter content, and B.O.D of the water samples could all contribute to the turbidity water samples (32). More so, the present study reported turbidity values lower than report of Ighalo and Adeniyi (2018) (33) carried out in Abuja Nigeria. This affirmed that there exist spatial differences in physical properties of borehole water within regions of the world (34) (35). Iron concentration changes indicate the existence of dissolved iron, which can lead to water coloring and perhaps alter taste and odor (36). Total alkalinity and total hardness levels in raw water samples represent mineral content and can influence water suitability for household and industrial use. Chloride and nitrate in raw water samples may suggest anthropogenic contamination from agricultural runoff or industrial discharges (31). The reduction in iron content in treated samples, combined with increase in alkalinity and total hardness, illustrates the treatment techniques' efficacy in eliminating dissolved minerals and improving water quality (37). However, the presence of residual aluminum in Sample D2, while at a low quantity, shows that more research and modification of treatment procedures are needed to reduce the presence of this component in the final water product.
The improved treatment system is poised to perform better than existing treatment designs in the study area and have capability of reducing physical-chemical-microbial parameters to levels within permissible limits of WHO and NSDWQ. These findings emphasize the significance of comprehensive water treatment techniques that include disinfection, pH control, and pollutant removal. Continuous monitoring and optimization of treatment procedures based on the individual problems associated with different water sources are critical to ensuring the public's access to safe and compliant drinking water.