Environmental Life Cycle Analysis of Manufacturing Options for Humanitarian Supplies: Drinking water containers

Purpose The purpose of this life cycle assessment (LCA) study was to determine the life cycle impacts for production and distribution of a humanitarian supply item under various supply chain paradigms in order to illustrate the potential environmental bene�ts of organizing production and supply operations for these items in novel ways. To do this a case study is used on a family-size water storage and dispensing bucket, such as the 14L-capacity polyethylene (PE) bucket commonly produced by Oxfam International. Methods The LCA is cradle-to-gate including production and transportation of PE plastic feedstock, fabrication of the water bucket


Introduction
With a both a large number and severity, a combination of crises have resulted in a record 339 million people that will need humanitarian assistance in 2023: one in every 23 people (UN OCHA, 2022).For example, acute food insecurity has grown to at least 222 million people and need urgent assistance, while 45 million people are at risk for starvation (UN OCHA, 2022).There is thus an urgent need for effective humanitarian responses to disasters as they occur, which can be focused on the logistical efforts to move goods (e.g., food or supplies) from where they are available to where people need them (Van Wassenhove, 2006; Kovács & Spens, 2007;Banomyong, et al., 2019).The eld of supply chain logistics for humanitarian responses is complex because it is challenging to forecast the demand because of the timing and location of a future disaster being unknown and the supply of aid as it is constrained by manufacturing potential and often funded by donations (De la Torre et al., 2019).Unfortunately, there can be a mismatch between both the quantity, type and timing of supplies delivered and the supplies that are needed in a given crises (Loy et al., 2016;James & Gilman, 2016).More than half of aid money is used to purchase these materials, so the mismatch wastes critical funds as well as negatively impacting the long-term economics of the regions suffering the disasters (James & Gilman, 2016).
With the open-source release of the self-replicating rapid prototyper (RepRap) 3-D printer (Sells et al., 2010;Jones et al., 2011;Bowyer, 2014) and the rapid innovation that ensued (De Jong & De Bruijn, 2012), the costs of additive manufacturing have decreased enough to make distributed manufacturing a threat to disrupt global value chains (Laplume et al., 2016).In fact, the costs have been reduced enough to make it viable in resource-constrained contexts like those found in impoverished communities, the developing world or during a crisis (Pearce et al., 2010).Thus, an approach to partially solve humanitarian aid issues gaining attention in humanitarian logistics circles is the concept of rapid manufacturing on site using 3-D printing (Tatham et Pearce & Qian, 2022) by reducing the amount of capital required for manufacturing locally.Distributed manufacturing also allows for customization (Gwamuri et al., 2014;Wittbrodt et al., 2015).This form of manufacturing for local needs during a disaster response, waste is eliminated as the only materials that need to be shipped to the disaster site are 3-D printers and feedstock, which need less space for storage and transport, are more durable and eliminate most packaging in a disaster response (Loy et al., 2016;James et al. 2016;Sniderman et al., 2023).New 3-D printers have been designed speci cally for humanitarian use (Savonen, et al., 2018;Lipsky et al, 2019).In addition, by only manufacturing what is needed on site, the mismatch that results in relief organizations shipping thousands of items that are not required and missing thousands of others that are required.
Perhaps even better than shipping 3-D printing feedstock to an area needing humanitarian aid, would be using local materials and then only needing to ship the equipment, which includes 3-D printers and recyclebots (waste plastic extruders that make lament for fused lament-based 3-D printers) (Baechler, et al., 2013;Zhong et al., 2017;Woern, et al., 2018;Mohammed et al., 2018a;b;2022).This approach has been proven successful with a range of common plastics including acrylonitrile butadiene styrene (ABS) (Mohammed et al., 2017;Zhong & Pearce, 2018), high density polyethylene (HDPE) (Baechler, et al., 2013;Chong et al., 2017;Mohammed et al., 2017;2019), linear low-density polyethylene (LLDPE) and lowdensity polyethylene (LDPE) (Hart et al., 2018); polypropylene (Pepi et al., 2017;Zander et al, 2019), and PET (Lee et al, 2013).In addition, there are open-source printers that can directly 3-D print ground plastic waste from a wide range of materials using fused particle fabrication/fused granular fabrication (FPF/FGF) at both the small scale (Volpato, et al., 2015;Whyman et al., 2018;Alexandre et al., 2020) and the large-scale cartesian based systems (Woern et al. 2018b;Byard et al., 2019;Reich, et al., 2019;Little, et al., 2020) and hangprinter/cable robot (Petsuik, et al., 2022).Finally, for materials which are hard to t into the distributed recycling and additive manufacturing (DRAM) method (Sanchez et al., 2017;2020), it is possible to 3-D print a mold and then extrusion mold into it (Dertinger et al., 2020).For these reasons 3-D printing appears to be particularly well-suited for humanitarian responses for everything from malnutrition identi cation bands (Michaels & Pearce, 2017) and housing (Gregory, et al., 2016) to vehicle repair (De la Torre, et al., 2016), surgical tools (Angela & Khan, 2015) and even surgical tables (Bow et al., 2022).Humanitarian relief non-pro t organizations are using this technique now including Refugee Open Ware (ROW) (Wharton et al., 2018), who 3-D prints prosthetics (Ramadurai, et al., 2019) and Field Ready, which 3-D prints medical devices (Saripalle, et al., 2016) like umbilical cord clamps (Dotz, 2015) and also has a long list of other approaches that are on the spectrum of full distributed manufacturing to localized central manufacturing (James & Gilman, 2016).These approaches include those that could be considered "do-it-together" where the success of the Do-It-Yourself (DIY) phenomenon is transferred to small and medium-sized enterprises (SMEs) (Dupont et al., 2021).In this approach networks of makerspaces, hackerspaces, factories, FabLabs or other spaces (e.g.libraries, schools or community centers) equipped with digital manufacturing tools like 3-D printers have enabled distributed production based on commons-based peer production off of open source designs in the 2022 digital commons (Fox, 2013;Pearce, 2014;Kohtala & Hyysalo, 2015;Dupont, 2019;2022).Although all these mechanisms to produce humanitarian goods are technically possible, both the economics and environmentally-most responsible solutions have not been determined.This study aims to ll that knowledge gap in relation to the environmental bene ts of one approach to another, which will provide insight into the long-term most sustainable approach.
The goal of this life cycle assessment (LCA) study was to determine the life cycle impacts for production and distribution of a humanitarian supply item under various supply chain paradigms in order to illustrate the potential environmental bene ts of organizing production and supply operations for these items in novel ways.To do this a case study is used on a family-size water storage and dispensing bucket, such as the 14L-capacity polyethylene (PE) bucket commonly produced by Oxfam International.The system boundary for this study is cradle-to-gate and includes the production and transportation of PE plastic feedstock, fabrication of the water bucket, and transportation of the bucket to a common distribution site representative of a humanitarian aid location.Three different humanitarian aid locations are used to illustrate the range of potential impacts for each processing and supply system: Nepal, South Sudan, and Peru.Six processing and supply scenarios were investigated, which are described in more detail below: 1) centralized Oxfam traditional system, 2) centralized commercial Chinese supply and distribution, 3) quasi-centralized Field Ready supply and distribution, 4) distributed supply and distribution system with 3-D printing, 5) distributed supply and distribution system with 3-D printing and local waste feedstock, and 6) distributed supply and distribution system with extrusion molding and local waste feedstock.The results are presented and discussed in terms of the environmental impact, logistics, and applications and future work.

Case study humanitarian aid product
Case study humanitarian aid product selected was the OXFAM Jerry Bucket, which is normally supplied by UNICEF for USD$5.34 as a 14L bucket with cap, and smooth handle (UNICEF, 2023).The bucket was designed primarily for the storage, transport, and dispensation of drinking water.It is made from virgin high density polyethylene (HDPE) and the lid is made from virgin low density polyethylene (LDPE), according to EN1186-3-9 standard (iTeh, 2002).The materials were selected to be tough, durable, UVresistant and food safe.The 14L bucket dimensions consist of a height of 300 mm, top diameter of 300/310 mm ± 5%, bottom diameter of 240 mm ± 5% and a wall thickness of 1.3 mm.Both the inside and outside of the bucket must be smooth: the gloss nish and curved inside surface prevents dirt and bacteria accumulation and eases cleaning and the outside smooth surface ensures comfort when carried on the head (UNICEF, 2023).The lid is meant to be tight-tting lid with rim-lock design, to prevent it from being removed, but it has a clip-on 100 mm ± 5% cap for lling with hand pumps and cleaning.Various humanitarian organizations produce these 14L buckets.A rendering of the Field Ready version of the bucket is shown in Fig. 1 and is used here throughout the analysis.The bucket weighs 0.86kg and the handle weighs 40g.

Life cycle assessment study methods
In this cradle-to-gate analysis, the use of the water bucket and nal disposal of the bucket are not included in the system boundary of this study, because these phases of the item life cycle will be common across all of the scenarios under study and therefore would not contribute to the differences observed in supply and production operations.
Global Warming Potential (GWP) is the environmental impact of interest in this study.The functional unit used for comparing scenarios will be the production and transportation of 200 buckets each with a 14liter capacity to a humanitarian aid location, which is the number of buckets assumed to t on a common pallet for shipping (Field Ready, 2023a).Three countries were selected because of historic disasters requiring humanitarian aid 1) Nepal for the 2017 ooding (Relief, 2017), 2) South Sudan for sporadic violence, chronic food insecurity and the devastating impact of major ooding in 2021 (UNHCR, 2023), and 3) Peru for oods, landslides and mudslides in 2011 (Relief, 2015 ).A prominent location in each of the three countries was used for each representative location for humanitarian aid distribution, which will described in more in each scenario.
The six processing and supply scenarios are described brie y below and summarized in Figs. 2 and 3. System 1: Oxfam traditional system.In Oxfam's traditional system of supply delivery, the buckets are manufactured in a low-cost location, such as India, and are transferred to a centralized distribution warehouse.The Oxfam Central facility in Oxford, England serves as the central single supplier for reshipping (Field Ready, 2023b).Virgin PE is sourced in India, buckets are manufactured using conventional injection molding in Pakistan, and the shipped to Oxford, England.When a humanitarian crisis occurs, buckets are shipped to the location of the crisis from England.Because of the large international shipping distances required, a combination of marine, rail, and road transport it used.System 2: Chinese supply and distribution.An alternative option for centralized production and transport would remove Oxfam international and do PE sourcing, bucket manufacturing using injection molding, and intermediate storage in the same general location.So, for example, Alibaba.com provides several sources of buckets ordered with a minimum of several thousand.For this system a location in eastern China was assumed to serve as the course for PE supply, bucket assembly, and storage.System 3: Field Ready supply and distribution system (https://www.eldready.org/buckets).In this more decentralized supply system, conventional virgin PE pellets are sourced from suppliers within the region of the country of interest, and local bucket manufacturing using injection molding is established at a key strategic location within the country of interest, eliminating one critical leg of transportation which is typically long, costly, and slow.System 4: Decentralized supply and distribution system with 3-D printing.In this system, the decentralized method of virgin PE sourcing and bucket manufacturing is adopted similar to system 3, but now it is assumed that the bucket manufacturing process is accomplished using FPF 3-D printing tools (Byard, et al., 2019) instead of injection molding systems, which are utility-intensive in comparison to 3-D printing.The printer assumed is the open source GigabotX, which is a commercial large format 3-D printer capable of printing the entire bucket (many desktop 3-D printers do not have the manufacturing volume capacity to print the 14L buckets).In addition, as it is FPF/FGF printer, only ground waste plastic or pellets is needed already sourced in the country.System 5: Distributed supply and distribution system with 3-D printing and local waste feedstock.In this system, the decentralized distribution system and 3-D manufacturing processes are similar to System 4, but it is assumed that the PE feedstock for 3-D printing comes from local waste PE such as drink bottles and is mechanically recycled into 3-D printing PE feedstock using well-established existing processes for DRAM.For this process the waste plastic would need to be cleaned, dried and shredded before putting into the FPF/FGF printer (Little et al., 2020).System 6: Distributed supply and distribution system with extrusion molding and local waste feedstock.This decentralized system utilizes locally-sourced waste plastic HDPE/LDPE, but replaces 3-D printing with an even lower-intensity manufacturing process, extrusion molding using a recyclebot as the extruder (Dertinger, et al., 2020).

Life cycle inventory data
To estimate the differences of electricity impacts in each manufacturing location, the local grid mixes were represented in the electricity pro le for each country (Table 1) using data from the International Energy Agency (IEA, 2022).Life cycle input data and commentary for each supply and distribution system are shown below in Tables 2-4.Life cycle inventory data comes from the Ecovinvent version 3 database (Wernet et al., 2016) unless otherwise noted.Data from Google Earth was used to estimate the shipping distances between port cities for transportation and cities for manufacturing and distribution in all the countries in the study, in addition to the existing information on the typical Oxfam supply chain system (Field Ready, 2023b).A standard injection molding process was used from the Ecoinvent database to model typical manufacturing impacts for Systems 1-3, while the FPF/FGF 3-D printing and extrusion manufacturing processes come from experimental data on the typical performance of these systems (Byard et al., 2019;Little et al., 2020).Manufacturing losses were estimated at 10% for injection molding and 1% for both of the decentralized 3-D printing and extrusion recyclebot-based processes.Additional scenarios will explore the impacts of manufacturing e ciency assumptions.Oxfam-produced buckets are slightly lighter than the decentralized buckets produced by Field Ready according to available information (172 kg vs 178 kg for the same 200-bucket functional unit), and each collection of 200 buckets is moved on a 17 kg pallet (Field Ready, 2023a).IPCC 100a Global Warming Potential (GWP) method was used to determine the amount of CO 2equivalent greenhouse gas (GHG) emissions as the environmental impact of interest for this study, in units of kg CO 2 − eq .Life cycle assessment modeling was performed in the SimaPro LCA modeling platform.

LCA Results and Discussion
The LCA results are shown in Figures 4, 5 and 6 for the GWP of the 6 supply and production scenarios, for each of the three target locations in the study, respectively.Appendix A contains Tables 5-7, which compile the numerical results.Several common observations can be seen across the results for all three locations, although the speci cs of shipping and utility use in each location also give rise to different impacts.For system 1 and 2 where shipping of large quantities of buckets was considered, 1 pallet could hold 200 buckets and weighed 172kg.
In general, System 2 (Chinese supply and distribution) performs better than System 1 (Oxfam typical process) due to the large reductions in shipping distance, even though the majority of that shipping distance is from relatively low-emissions marine shipping.For System 2, however, there would be concern amongst aid organization that are too scared out reliability /delivery time from ordering under disasterrelated contexts at a site like Alibaba.For this model to work the NGOs would need to do some preordering and testing, but there is an economic barrier of having to order thousands (e.g.5,000) at a time.
Transitioning from System 2 to System 3 (local injection molding) typically results in lower overall emissions by trading off higher material shipping impacts for lower manufacturing emissions, in Nepal and Peru, due to the lower embodied emissions associated with electricity.This is not the case in South Sudan, where electricity production produces even more GHGs than in China due to the reliance on oil for electricity.This conversion to more distributed production indicates the importance of the local electricity supply.
System 4 (local 3-D printing of virgin plastic) typically results in higher emissions than System 3, due to the reliance on electricity for FPF/FGF 3-D printing.This underscores the importance of the emissions intensity of the grid for choosing an ideal location to do manufacturing.Locations with low emissions (e.g.Quebec) would systematically do better.In addition, it is straight-forward to power the 3-D printing devices with solar photovoltaic technology so that rapid manufacturing can take place on site without reliable power with no emissions (King et al., 2014;Gwamuri, et al., 2016;Khan et al. 2018).Future work is needed to investigate this scenario, which may be realistic in the case of humanitarian crises.It also points to areas of future work to improve printing speed, throughput, multi-nozzle 3-D printing and other areas that could enable more rapid and more e cient manufacturing with 3-D printing.
The real bene t of local 3-D printing, however, starts to be realized in the DRAM System 5 (waste plastic local FPF 3-D printing), due to the elimination of the emissions associated with virgin plastic, assuming that all of the necessary plastic can be recovered within a 50 km radius of the manufacturing locationquite likely, this supply radius is a very conservative estimate and material supply impacts could be even lower.The South Sudan scenarios for System 4 and 5 still appear worse than the System 1 baseline, however, due to the extremely large electricity emissions in that country.Again, any country that wants to be favored for manufacturing from those seeking low-embodied emissions should be aggressively eliminating fossil carbon sources from the supply.
Even further emissions reductions are possible with the transition to extrusion molding with the recyclebot extrusion molding system (System 6), which offers a 95% reduction in manufacturing electricity usage compared to 3-D printing.This system change is enough to drive the GHG emissions for the Nepal and Peru scenarios to greater than 94%, and also brings the South Sudan case back to being largely environmentally favorable, with a 90.9% GHG emissions reduction compared to System 1.This path is also perhaps the most realistic as for humanitarian products like a bucket, where they are relatively large 3-D prints and many identical ones would be adequate the extrusion molding system can make use of DRAM (e.g.  8, where the manufacturing e ciency for regular injection molding was changed from 10% down to 5%, and the manufacturing failure rate of 3-D printing was increased from 1% to 10%.This impacts the amount of raw material that is required to be produced, shipped, and transformed during the manufacturing phase, but should not affect the nal shipping stage of this LCA study.This does have the effect of lowering the GHG emissions associated with supply Systems 1, 2, and 3 and increasing the emissions of systems 4, 5, and 6, but the overall results are still consistent with the general observations discussed above, that signi cant GHG emissions reductions are possible from distributed manufacturing and local procurement of waste feedstock.Changes in overall results are generally less than 5% due to these changes in assumed manufacturing e ciency.This effect is similar for the Peru target location (Appendix A Table 9) and the South Sudan location (Appendix A Table 10), although the impacts of changing manufacturing e ciency in situations where manufacturing is being performed in South Sudan do have more of an impact due again to the large emissions associated with electricity production.

Conclusions
This examined the effects of manufacturing and distributing an OXFAM Jerry Bucket, a family-size water storage, and dispensing bucket with a 14L capacity, in Nepal, Peru, and South Sudan under six distinct supply chain models.During the LCA, it has been observed that two factors have the major contribution to total GHG emissions: i) electricity usage for manufacturing and ii) shipping feedstock and nal product.Among System 1-3, System-1 and System 2 are environmentally poor as the electricity emission in Pakistan and China is quite high.Emissions from System 2, however, is marginally lower overall than System 1 due to the signi cant reduction in shipping distance.On the other hand, System 3 showed convenience as the products are manufactured locally.Nepal and Peru's electricity mix includes more than 50% of hydropower; therefore, almost 57%-60% of emission reduction can be observed in manufacturing.
Nevertheless, a 7% increase has been perceived in the South Sudan location, as 100% of their total electricity production relies on oil.There a decentralized supply and distribution system with 3-D printing (System 4) seems less compatible due to the massive contribution of nearly 72% of GHG emissions associated with manufacturing.The FPF/FGF GigabotX 3-D printer relies on local electricity makes it one of the less appropriate methods for the three targeted locations for now, even considering the optimistic assumptions.In system 5, the same equipment has been used, but with local waste feedstock, which shows an improvement of 67.7% for Nepal and 65.5% for Peru because of the reduced shipping emissions, even if the manufacturing emission is the highest among all of the systems.Yet, system 5 shows the worst scenario for South Sudan.System 6 (distributed supply and distribution system with extrusion molding and local waste feedstock) is feasible for all three locations.This cradle-to-gate life cycle assessment has a 90.9%-97.4% improvement in favorable situations and less than a 1% reduction under pessimistic assumptions.
System 4 and 5 seem less feasible for locations with heavy fossil fuel percentages on the grid because of their reliance on electricity from the manufacturing location.If manufacturing could be done where the electricity emission is lower, i.e., Quebec, these systems can be feasible.Furthermore, it has been vividly seen that using local waste feedstock is the most e cient approach; however, a further study should be done on operating the FPF/FGF 3-D printer or extrusion molding systems powered with distributed photovoltaic systems in order to complement this process and produce the most environmentally responsible production.LCA results for Peru.
Figure 6 LCA results for South Sudan.
Page 27/29 LCA comparison between optimistic and pessimistic scenarios for Nepal.
Figure 8 LCA comparison between optimistic and pessimistic scenarios for Peru.

Figure 1 A
Figure 1

Figure 2 Summary
Figure 2

Figure 3 Map
Figure 3

Table 1
Electricity grid mix assumptions used in this study(IEA, 2022)

Table 4
Life cycle input data for South Sudan location scenarios.
alternate set of LCA results are shown in Figures 7, 8 and 9 and are presented in Appendix A Table (Wittbrodt et al., 2013)at low errors were used for the distributed processes and thus low sources of waste.This would appear likely after experience is gained, but before that 3-D printing errors can be as high as 10% or more(Wittbrodt et al., 2013).To illustrate the impacts of manufacturing e ciency in this system, an