The milling process of SiCp/Al composites with high volume fraction and large particle size has been studied in this paper. The stress and strain distribution of SiC reinforced particles and the removal mechanism of the material are analysed. The effects of milling depth and feed per tooth on surface quality were analysed. The effect of feed per tooth on the thickness of subsurface damage layer is revealed. The results show that in the end milling process of high volume fraction SiCp/Al composites, the blade diameter is larger relative to the particle size, which leads to the main removal forms of particle size: extrusion crushing and rolling crushing. The surface defects of the machined workpiece mainly include cavity, crack and delamination caused by extrusion of aluminum matrix. The surface quality of the machined workpiece can be improved by increasing the milling depth appropriately. The increase of the feed rate of each tooth will lead to the increase of the surface defect of the machined workpiece and the deterioration of the surface quality. When the feed rate per tooth increases from 4 to 8 µm, the thickness of subsurface damage increases from 47.7 to 60.5 µm. It found that the ratio between the minimum cutting thickness of SiCp/Al composites and the radius of the cutting edge should be less than or equal to 4%.