Oily wastewater has always been an environmental issue that we are concerned about and committed to managing. Although the superwetting membranes have been extensively studied and widely used in oil/water separation, the abundant discarded membranes are still headaches due to their non-degradable nature. In this work, all-around green, as well as superhydrophilic polylactic acid (PLA) nonwoven membrane, is designed by coating cellulose nanospheres (CNCs) with the aid of polydopamine (PDA). Abundant hydroxyl groups and hierarchical rough structure synergistically contribute to the superhydrophilicity and excellent oil/water separation performance of the resultant CNCs/PDA/PLA nonwoven membrane. Interestingly, the oil/water separation efficiency can be maintained above 98% after 100 times of repeated use. With outstanding durability, and easy controllability, the CNCs/PDA/PLA nonwoven membrane may provide effective solutions to simultaneously manage the oily wastewater and secondary pollution of the used membrane itself.

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This is a list of supplementary files associated with this preprint. Click to download.
Scheme 1. Schematic illustration of the preparation of the superhydrophilic CNCs/PDA/PLA nonwoven membrane for oil/water separation.
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Posted 08 Jun, 2021
Received 04 Jun, 2021
On 02 Jun, 2021
On 30 May, 2021
On 28 May, 2021
Posted 08 Jun, 2021
Received 04 Jun, 2021
On 02 Jun, 2021
On 30 May, 2021
On 28 May, 2021
Oily wastewater has always been an environmental issue that we are concerned about and committed to managing. Although the superwetting membranes have been extensively studied and widely used in oil/water separation, the abundant discarded membranes are still headaches due to their non-degradable nature. In this work, all-around green, as well as superhydrophilic polylactic acid (PLA) nonwoven membrane, is designed by coating cellulose nanospheres (CNCs) with the aid of polydopamine (PDA). Abundant hydroxyl groups and hierarchical rough structure synergistically contribute to the superhydrophilicity and excellent oil/water separation performance of the resultant CNCs/PDA/PLA nonwoven membrane. Interestingly, the oil/water separation efficiency can be maintained above 98% after 100 times of repeated use. With outstanding durability, and easy controllability, the CNCs/PDA/PLA nonwoven membrane may provide effective solutions to simultaneously manage the oily wastewater and secondary pollution of the used membrane itself.

Figure 1

Figure 2

Figure 3

Figure 4

Figure 5

Figure 6

Figure 7

Figure 8
This is a list of supplementary files associated with this preprint. Click to download.
Scheme 1. Schematic illustration of the preparation of the superhydrophilic CNCs/PDA/PLA nonwoven membrane for oil/water separation.
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