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Research Article
Mohammad Jawaid
Universiti Putra Malaysia
Corresponding Author
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In this study, poly(lactic acid) (PLA)/poly(butylene succinate) (PBS) dual-layer membranes filled with cellulose nanowhisker (CNWs), were fabricated by employing an integrated method combining water vapor-induced and crystallization-induced phase inversions. Four membranes (denoted as C-neat, C-I, C-II, and C-III) loaded with CNWs in the range of 0-3 wt% were prepared and characterized using various materials research aspects. The use of CNWs fillers was found to synergize the precipitation of the polymer layers in the integrated water vapor-induced and crystallization-induced method. With morphological examination, the C-III membrane showed prominent and well-laminated two layers structure, evidencing the great precipitating effect of 3 wt% CNWs on the crystallization the polymeric layers. The increase in CNWs loadings was found to improve the membrane porosity with, which was accompanied by a decrease in the pore size. The heat resistance of C-neat membrane was enhanced by CNWs loading of 1 wt% (C-I) whereas it decreased with loadings of 2 and 3 wt% (C-II and C-III) due to flaming behaviour of sulphated nanocellulose. Furthermore, The C-III membrane displayed the best mechanical properties in with respect to tensile strength, elongation at break and Young’s modulus compared to other membrane samples. For wastewater filtration performance, the continuous operation test showed that C-III membrane exhibited the highest removal efficiency for both Co2+ and Ni2+ metal ions reaching 83 and 84%, respectively. Thus, it can be concluded that CNWs filled dual-layer membranes have a strong potential for future development for the removal of heavy metal ions from wastewater streams.
Keywords
Poly(lactic acid), Poly(butylene succinate), Cellulose nanowhisker, Dual-layer membranes.
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Received 31 May, 2021
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This preprint is under consideration at Cellulose. A preprint is a preliminary version of a manuscript that has not completed peer review at a journal. Research Square does not conduct peer review prior to posting preprints. The posting of a preprint on this server should not be interpreted as an endorsement of its validity or suitability for dissemination as established information or for guiding clinical practice.
Learn more about In Review
Research Article
Mohammad Jawaid
Universiti Putra Malaysia
Corresponding Author
Badges
Prescreen
This manuscript passed our Prescreen assessment
Complete author information
Appropriate declaration statements
Potential risks to human health
Prescreen
Peer Review Timeline
CURRENT STATUS: Under Review
Version 1
Posted 01 Jun, 2021
No community comments so far
Reviews received
Received 31 May, 2021
Reviewers invited
Invitations sent on 28 May, 2021
Editor invited
On 27 May, 2021
Editor assigned
On 20 May, 2021
First submitted
On 10 May, 2021
Metrics
Comments: 0
PDF Downloads: ...
HTML Views: ...
License:
This work is licensed under a CC BY 4.0 License. Read Full License
In this study, poly(lactic acid) (PLA)/poly(butylene succinate) (PBS) dual-layer membranes filled with cellulose nanowhisker (CNWs), were fabricated by employing an integrated method combining water vapor-induced and crystallization-induced phase inversions. Four membranes (denoted as C-neat, C-I, C-II, and C-III) loaded with CNWs in the range of 0-3 wt% were prepared and characterized using various materials research aspects. The use of CNWs fillers was found to synergize the precipitation of the polymer layers in the integrated water vapor-induced and crystallization-induced method. With morphological examination, the C-III membrane showed prominent and well-laminated two layers structure, evidencing the great precipitating effect of 3 wt% CNWs on the crystallization the polymeric layers. The increase in CNWs loadings was found to improve the membrane porosity with, which was accompanied by a decrease in the pore size. The heat resistance of C-neat membrane was enhanced by CNWs loading of 1 wt% (C-I) whereas it decreased with loadings of 2 and 3 wt% (C-II and C-III) due to flaming behaviour of sulphated nanocellulose. Furthermore, The C-III membrane displayed the best mechanical properties in with respect to tensile strength, elongation at break and Young’s modulus compared to other membrane samples. For wastewater filtration performance, the continuous operation test showed that C-III membrane exhibited the highest removal efficiency for both Co2+ and Ni2+ metal ions reaching 83 and 84%, respectively. Thus, it can be concluded that CNWs filled dual-layer membranes have a strong potential for future development for the removal of heavy metal ions from wastewater streams.
Figure 1
Figure 2
Figure 3
Figure 4
Figure 5
Figure 6
Figure 7
Figure 8
Figure 9
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