This preprint is under consideration at Environmental Earth Sciences. A preprint is a preliminary version of a manuscript that has not completed peer review at a journal. Research Square does not conduct peer review prior to posting preprints. The posting of a preprint on this server should not be interpreted as an endorsement of its validity or suitability for dissemination as established information or for guiding clinical practice.
Learn more about In Review
Research Article
Keli Yang
Qinghai Institute of Salt Lakes, Chinese Academy of Sciences
Corresponding Author
License:
This work is licensed under a CC BY 4.0 License. Read Full License
The abundance and chemical composition of dissolved organic matter (DOM) in the brine of solar ponds influence efficiency of mineral extraction and rates of brine evaporation, and cause undesired odor and color of the products. In this paper, we report an investigation on changes of DOM compositions in solar ponds from salt lake brine through different approaches. The results showed that the DOM was primarily composed of carbohydrates, aliphatic and aromatic compounds. Dissolved organic carbon (DOC) analysis revealed that the concentration of DOC in solar pond increased with exposure time, and up to 15−fold upon evaporation/irradiation of salt lake brine. Analyses with the elemental composition, Fourier transform infrared spectroscopy (FTIR) and cross polarization magic angle spinning (CP/MAS) 13C nuclear magnetic resonance (NMR) indicated that the relative abundance of aliphatic compounds (including functionalized ones) increased in solar pond process, while an opposite phenomenon was observed for carboxylic acid moieties, aromatics and carbohydrates. Pyrolysis−gas chromatography−mass spectrometry (Py−GC−MS) revealed that most of the DOM in salt lake brine contained methylene chain, terpenoid-like, carbohydrate and/or aromatic structures. The presence of some sulfur-containing organics implied some anaerobic biotic decays, but microbiological processes were probably subordinate to photo-induced DOM transformations. In the salt lake brine, exposure-driven decay decreased the abundance of polysaccharides and increased that of mono- and polyaromatic pyrolysis products. Finally, the implications and guidelines for removing DOM from brine in the process of brine resource exploitation were discussed.
Keywords
Dissolved organic matter, Salt lake brine, Solar pond, Mineral extraction, Transformations
Figure 1
Figure 2
Figure 3
This is a list of supplementary files associated with this preprint. Click to download.
- SupplementaryMaterial.doc
Supplementary Material
Loading...
Badges
Prescreen
This manuscript passed our Prescreen assessment
Complete author information
Appropriate declaration statements
Potential risks to human health
Prescreen
Peer Review Timeline
CURRENT STATUS: Under Review
Version 1
Posted 09 Jul, 2021
No community comments so far
Reviewers invited
Invitations sent on 05 Jul, 2021
Editor assigned
On 04 Jun, 2021
First submitted
On 03 Jun, 2021
Metrics
Comments: 0
PDF Downloads: ...
HTML Views: ...
Learn more about our company.
This preprint is under consideration at Environmental Earth Sciences. A preprint is a preliminary version of a manuscript that has not completed peer review at a journal. Research Square does not conduct peer review prior to posting preprints. The posting of a preprint on this server should not be interpreted as an endorsement of its validity or suitability for dissemination as established information or for guiding clinical practice.
Learn more about In Review
Research Article
Keli Yang
Qinghai Institute of Salt Lakes, Chinese Academy of Sciences
Corresponding Author
Badges
Prescreen
This manuscript passed our Prescreen assessment
Complete author information
Appropriate declaration statements
Potential risks to human health
Prescreen
Peer Review Timeline
CURRENT STATUS: Under Review
Version 1
Posted 09 Jul, 2021
No community comments so far
Reviewers invited
Invitations sent on 05 Jul, 2021
Editor assigned
On 04 Jun, 2021
First submitted
On 03 Jun, 2021
Metrics
Comments: 0
PDF Downloads: ...
HTML Views: ...
License:
This work is licensed under a CC BY 4.0 License. Read Full License
The abundance and chemical composition of dissolved organic matter (DOM) in the brine of solar ponds influence efficiency of mineral extraction and rates of brine evaporation, and cause undesired odor and color of the products. In this paper, we report an investigation on changes of DOM compositions in solar ponds from salt lake brine through different approaches. The results showed that the DOM was primarily composed of carbohydrates, aliphatic and aromatic compounds. Dissolved organic carbon (DOC) analysis revealed that the concentration of DOC in solar pond increased with exposure time, and up to 15−fold upon evaporation/irradiation of salt lake brine. Analyses with the elemental composition, Fourier transform infrared spectroscopy (FTIR) and cross polarization magic angle spinning (CP/MAS) 13C nuclear magnetic resonance (NMR) indicated that the relative abundance of aliphatic compounds (including functionalized ones) increased in solar pond process, while an opposite phenomenon was observed for carboxylic acid moieties, aromatics and carbohydrates. Pyrolysis−gas chromatography−mass spectrometry (Py−GC−MS) revealed that most of the DOM in salt lake brine contained methylene chain, terpenoid-like, carbohydrate and/or aromatic structures. The presence of some sulfur-containing organics implied some anaerobic biotic decays, but microbiological processes were probably subordinate to photo-induced DOM transformations. In the salt lake brine, exposure-driven decay decreased the abundance of polysaccharides and increased that of mono- and polyaromatic pyrolysis products. Finally, the implications and guidelines for removing DOM from brine in the process of brine resource exploitation were discussed.
Figure 1
Figure 2
Figure 3
Loading...