Semiquantitative Characterizations And Controlling Factors of Microscopic Pore Characteristics of The Metamorphic Rock Reservoir In The Central Paleo-Uplift Belt, Songliao Basin

Currently, metamorphic rock is a common target for oil and gas exploration, and reservoirs are the key factors restricting hydrocarbon exploration and development in metamorphic rocks. The deep metamorphic rock gas reservoir in the central paleo-uplift of the northern Songliao Basin has good exploration and development potential. In this study, we use a combination of qualitative descriptions and quantitative analysis to comprehensively analyze the pore characteristics of the reservoir and explore the factors controlling the pore characteristics of the metamorphic rock reservoir in the central paleo-uplift belt of the Songliao Basin. The metamorphic rock reservoir in the central paleo-uplift belt contains three types of lithologies: chlorite schist, mylonite, and mica schist, each with different protoliths and metamorphic histories. The reservoir space can be divided into 4 pore types, and the reservoir space of each lithology is quite different. The results of high-pressure mercury intrusion and nitrogen adsorption indicate that the pore size distributions of the schist and mylonite differ. Compared with the schist, the mylonite has less reservoir space, stronger homogeneity, larger pore size, smaller specic surface area, more natural gas reservoir space and stronger natural gas adsorption capacity. This paper also studies the formation process of the reservoir and divides it into four stages. Finally, this article discusses in detail the factors controlling the microscopic pore characteristics of metamorphic rock reservoirs in the central paleo-uplift belt; the metamorphic rock protolith is the most important controlling factor.


Introduction
Currently, metamorphic rock is a common target for oil and gas exploration, and reservoir properties are the key factors restricting hydrocarbon exploration and development in metamorphic rocks 1,2 . It is now generally believed that the most important reservoir space in metamorphic rock reservoirs is fractures 3,4,5,6 . Therefore, through core observation and imaging logging, many scholars have nely characterized fractures, including the length, width, density, opening, dip of fractures, and the angle between ground stress and the strike of fractures (to judge whether the fracture is easy to open during fracturing), and have studied the formation, evolution stages and classi cation of fractures and whether there is ll and the nature of the ll 1,2,3,5,7,8,9 . At present, research on fractures in metamorphic rock reservoirs is relatively mature 3,9 . It is undeniable that fractures have a very important impact on the gas production of metamorphic rock reservoirs. However, in addition to fractures, there are many pores and micro ssures that are invisible to the naked eye and cannot be identi ed by image logging in metamorphic rock reservoirs 9,10 . Similar to shale, these microscopic pores and micro ssures can also become reservoir spaces and ow channels for natural gas, and fracturing technology makes production of natural gas from smaller pores possible 11 . Therefore, it is necessary to study the microscopic pores in metamorphic rock reservoirs. The combination of microscopic pores and macroscopic fractures can provide a more comprehensive understanding of the reservoir space in metamorphic rock reservoirs.
The pore characteristics of the metamorphic rock reservoir are relatively underexplored 12,13 . At present, research on metamorphic rock reservoirs is mainly based on fracture characterization and well logging identi cation, and there are few studies on the pore characteristics of metamorphic rock reservoirs and the factors that control them 6,9 . Considerable controversy continues over the factors controlling the pore structure of metamorphic rock reservoirs. Xia et al. propose that the degree of metamorphism has a great impact on reservoir properties 14 , and Zhu et al. suggest that the lithology of metamorphic rocks is a core factor controlling reservoir formation and the preservation of reservoir space 15 . Han et al. suggest that the main factors controlling metamorphic reservoir development are temperature, lithology, minerals, dissolution, faults, and paleogeomorphology 1 . The research of Liu et al. has focused on rocks that have undergone contact metamorphism, and they conclude that the properties of metamorphic rocks are mainly controlled by lithology and diagenesis before intrusion 16 . Previous studies that have conducted research on reservoir pore characteristics have used mainly qualitative methods. In this study, we selected the cores of metamorphic rock reservoirs with underdeveloped macroscopic fractures using a combination of qualitative descriptions (thin section analysis, thin sections and scanning electron microscopy) and quantitative analysis (high-pressure mercury intrusion and nitrogen adsorption-desorption) to comprehensively analyze the pore characteristics of reservoirs and explore the factors controlling the pore characteristics of the metamorphic rock reservoir in the central paleo-uplift belt of the Songliao Basin in an attempt to provide ideas for improving the evaluation system of metamorphic rock gas reservoirs and provide guidance for the exploration of metamorphic rock gas reservoirs.

Geological Setting
The Songliao Basin is an important petroliferous basin in northeastern China that has three major structural sequences: a depression sequence, a faulted sequence, and the basement. A large number of oil elds, represented by the Daqing Changyuan superlarge oil eld, and a large number of natural gas elds, represented by the Xujiaweizi gas eld, have been discovered in the depression sequence 17,18 . However, the exploration level of hydrocarbon resources in the basement of the Songliao Basin is still very low and is still in its infancy.
The investigated districts are located in the central paleo-uplift belt, which is located between the Xujiaweizi fault depression and the Gulong fault depression in the north ( Fig. 1-a) and is a buried hill-like uplift zone formed on a basement containing thrust folds. The strata below the second member of the Denglouku Formation are absent above the basement, and the Denglouku Formation directly overlaps it.
In the three main salients in the central paleo-uplift belt, namely, the Wangjiatun salient, Zhaozhou salient and Changde salient, three risk wells were developed: the LT1, LT2 and LTX3 wells ( Fig. 1-a). Among them, wells LT1 and LT2 reveal a metamorphic rock reservoir in the basement and have good natural gas shows. The daily gas production rate of the metamorphic rock reservoir in the LT1 well is 1.0×10 4 m 3 , and that of the LT2 well is 3.6×10 4 m 3 18 , which shows that the basement of the central paleo-uplift belt has good exploration potential and is an important strategic area for hydrocarbon resources in the Songliao Basin 19,20 .

Petrological Characteristics Of Metamorphic Rock Reservoir
The lithologies revealed by the LT1 and LT2 wells are mainly metamorphic rocks. The basement revealed in the LT1 well can be divided into three lithological members: the lower member is mica schist, the middle member is mylonite, and the upper member is chlorite schist ( Fig. 1-b). The basement revealed in the LT2 well can be divided into two lithological members: the lower member is mylonite, and the upper member is unmetamorphosed granite (Fig. 1-c). This article focuses only on metamorphic rocks. Two samples were taken from each lithological member. The speci c information is shown in Table 1. The chlorite schist (Samples 1 and 2) in the LT1 well has a blasto-pilotaxitic texture ( Fig. 2-a) and schistose structure ( Fig. 2 Fig. 2-b); albites have an ocellar structure ( Fig. 2a). Therefore, the protolith of chlorite schist is andesite that experienced dynamic metamorphism.

Mica schist
The mica schist (Samples 3 and 4) in well LT1 has a porphyritic crystalloblastic texture, ne granular lepidoblastic texture and schistose structure and is mainly composed of quartz (approximately 25 vol.%), feldspar (approximately 25 vol.%), chlorite (approximately 12 vol.%), mica (including biotite and muscovite, approximately 35 vol.%) and garnet (approximately 3 vol.%). Quartz and feldspar grains are separated by directionally aligned biotite and muscovite. Faint blastopsammitic structure ( Fig. 2-d) can be observed. The abundance of micas implies that the rock contained mud, so the protolith was a clastic rock, and the metamorphism was regional.

Mylonite
The mylonite (Samples 5, 6, 7, and 8) in the LT1 and LT2 wells has a blastogranitic texture, deformation lamella and mica sh ( been dynamically recrystallized and oriented, retaining the granitic structure of the protolith. The feldspar grains are subhedral, the quartz grains are allotriomorphic, and there are no signs of transport. In summary, the protolith was a granite, and the metamorphism was dynamic.

Field emission scanning electron microscopy (FE-SEM)
Field emission scanning electron microscopy (FE-SEM) experiments were carried out at the Test Science Experiment Centre of Jilin University. The microstructural morphology of the metamorphic rocks was observed using JSN-6700F equipment. The samples were cut into slices with a length and width of 1 cm and 1 mm thickness and subjected to ion polishing. All images were obtained under a high vacuum mode with an 8 kV voltage. The working distance was approximately 10 mm.

High-pressure mercury intrusion (HPMI)
High-pressure mercury intrusion (HPMI) experiments were conducted with a Micromeritics AutoPore IV 9520 system at the Beijing Centre for Physical and Chemical Analysis. The maximum intrusion pressure was 30000 psia (206.8 MPa), corresponding to a pore throat diameter of 6.6 nm. The experimental process was as follows: samples were loaded into the core chamber and vacuum pumped for 1 h. After mercury had lled the core chamber, measuring valves and balance valves were opened. Then, mercury was injected gradually under an applied pressure to measure the capillary pressure. Once a maximum pressure of 30000 psia was reached, the pressure started to decrease progressively, and mercury was extruded from the sample. Capillary pressure curves were derived by Micromeritics AutoPore IV 9520 software. The pore size distribution (PSD) was calculated according to the Washburn equation. The laboratory procedure followed Standard GB-T 21650.1-2008.

Nitrogen adsorption-desorption experiments
Nitrogen adsorption-desorption experiments were carried out at the Test Science Experiment Centre of Jilin University. Prior to adsorption measurements, all metamorphic rock samples were prepared by sieving to a size of 50-80 mesh and then weighing 2-6 g per sample. The samples were dried at 200°C for 6 h in a vacuum oven to remove moisture and volatile gases from the rocks. The Micromeritics ASAP2020 automatic device was used in the experiment, measuring the gas adsorption volume over the relative equilibrium adsorption pressure (P/P 0 ) range of 0.01-0.99, and the determinations of adsorption isotherms and outgassing were carried out in a liquid nitrogen environment.

Microscopic pore types and morphological characteristics
Clay minerals can be identi ed by scanning electron microscopy. The chlorite schist contains many chlorites ( Fig. 3-a), and the mica schist has the most types of clay minerals, including biotite, chlorite and a small amount of montmorillonite ( Fig. 3-e), while mylonite has only a very small amount of chlorite. Based on previous studies 14, 22 on the classi cation of metamorphic rock reservoir space and this study, the reservoir space of the metamorphic rock reservoir in the central paleo-uplift belt can be divided into the following four types: intergranular pores, dissolved pores, structural microfractures and weathering microfractures ( Table 2). The main reservoir space in the chlorite schist is in the form of intergranular pores and weathering microfractures; the main reservoir space in the mica schist is in the form of intergranular pores and dissolved pores; and the main reservoir space in the mylonite is in the form of dissolved pores, weathering microfractures and structural microfractures.  23,24 . The PSD that can be detected by HPMI is between 7.1 nm and 208 µm, and the PSD that can be detected by nitrogen adsorption is between 0.858 nm and 233.913 nm 25 . For the characterization of pore structures less than 200 nm, nitrogen adsorption-desorption is more accurate than HPMI. Therefore, the HPMI method is used to characterize pores larger than 200 nm, and the nitrogen adsorption method is used to characterize pores smaller than 200 nm 26 . Figure 4 presents the high-pressure mercury capillary curves of schist and mylonite. The gure shows that the mercury entry curve changes from slow to steep, indicating more large pores and fewer small pores. The curve is generally linear, indicating poor pore sorting. The calculated mercury intrusion parameters are shown in Table 3. The average porosity of schist is 1.46%, the average porosity of mylonite is 1.00%, and the porosity of schist is higher than that of mylonite.
The displacement pressures of the metamorphic rock samples are very low. For the schist, the maximum value is 0.0643 MPa, and the average value is 0.0425 MPa. The maximum displacement pressure of the mylonite is only 0.0255 MPa, and the average is 0.0232 MPa (Table 3), which is signi cantly less than that of the schist, indicating that the mylonite has a larger maximum pore throat and higher permeability 27 . The maximum mercury saturation can re ect the heterogeneity of the reservoir. The maximum mercury saturation of schist is 73.64% on average, while that of the mylonite is 84.32% on average (Table 3), re ecting that the schist is more heterogeneous and that mylonite is more homogeneous. The retreat mercury curves of the schist and mylonite are linear, and a large amount of mercury is withdrawn at the rst point of pressure reduction. After this point, there is very little mercury withdrawal. The withdrawal e ciencies are very low, with values of 30.25% for the schist and 24.84% for the mylonite on average (Table 3). The pore distribution of metamorphic rock reservoir samples is shown in Fig. 5. It can be seen from the gure that the chlorite schist has the narrowest pore size distribution, the mylonite has a wider pore size distribution, and the mica schist has the widest pore size distribution. This shows that the heterogeneity of the mica schist is the strongest. Figure 6 presents the adsorption isotherms of the samples. When the relative pressure is very low, the nitrogen exhibits micropore lling and monolayer adsorption. As the relative pressure increases, the nitrogen molecules in the rst layer reach saturation, and a relatively obvious in ection point appears in the isotherm adsorption curve (point B in Fig. 6, taking Sample 3 as an example, re ecting the existence of macropores and mesopores); then, multilayer adsorption occurs in the metamorphic rocks. As the relative pressure increases, the number of nitrogen molecule adsorption layers gradually increases. When the relative pressure rises to a certain value, the nitrogen gas in the pores starts to condense 25 . None of the samples show a horizontal plateau at a relative pressure close to 1, illustrating that metamorphic samples still contain a range of macropores that cannot be analyzed by nitrogen adsorption-desorption experiments 28 . The adsorption quantity in the schist is much higher than that in the mylonite, indicating that the schist has more pore space than the mylonite.

Characteristics by nitrogen adsorption-desorption experiments
The type of adsorption isotherm and the shape of the hysteresis loop can indicate the pore type of a porous medium 26 . According to the International Union of Pure and Applied Chemistry (IUPAC) classi cation, the schist has type II adsorption isotherms, and the mylonite has type III adsorption isotherms. The branch of the adsorption curve and the branch of the desorption curve do not coincide, forming a hysteresis loop that is caused by processes involving adsorption into and desorption from mesopores 24 . According to the IUPAC classi cation, the schist and mylonite have both H3-type loops and H4-type loops, indicating that the sample pore types are mainly at, slit-like and ink bottle-shaped.
The results of nitrogen adsorption require the use of different data processing methods, such as the Brunauer-Emmett-Teller (BET) 29,30 , Barrett-Joyner-Hallenda (BJH) 31 and density functional theory (DFT) models 32 . Nitrogen adsorption can yield three important parameters: speci c surface area, average pore diameter and speci c pore volume ( Table 4). The BET method is suitable for calculating speci c surface area, the BJH method is suitable for calculating average pore diameter, and the DFT method is suitable for calculating speci c pore volume 25 . The speci c pore volume of the schist is greater than that of the mylonite, which is consistent with the HPMI results. The speci c surface area of the schist is also greater than that of the mylonite, while the average pore size is smaller than that of the mylonite. The BJH model cannot provide a realistic description of the lling of micropores or even smaller mesopores 33 , so we applied the DFT molecular model adsorption branch due to its applicability in determining the PSD at both the micropore (pore sizes < 2 nm) and mesopore (pore sizes between 2 nm and 50 nm) scales 26,34 . Figures 7 and 8 show the PSDs of the samples based on the DFT theory, clearly illustrating the PSD below 200 nm, lling the gap of insu cient detection range and accuracy from HPMI.
The PSD curve of the schist exhibits multimodal characteristics, with several maximum pore diameter values larger than 2 nm (Fig. 7). The mylonite has almost no pores smaller than 10 nm, and its pores are mainly distributed between 50 nm and 200 nm (Fig. 8).

Pore fractal characteristics
Fractal geometry has a strong ability to describe the irregular or fragmented shapes of natural features as well as other complex objects that traditional Euclidean geometry fails to characterize 35 . The fractal dimension (D) is the key parameter in fractal geometry and provides a systematic approach to quantifying irregular patterns 36,37 . The fractal Frenkel-Halsey-Hill (FHH) model has been proven to be the most effective method for analyzing the fractal behavior of porous media 38 . The FHH model, which has been widely recognized and used 1,26,38,39 , can be described using the following Eq. 3 8 : where V is the quantity of adsorbed nitrogen gas at equilibrium pressure P, V 0 is the volume of monolayer coverage and P 0 is the saturation pressure.
According to the equation, on the plot of lnV vs ln (ln (P 0 /P)), the slope of the straight line should be equal to D-3. The FHH plots of metamorphic samples are shown in Fig. 8 and clearly show that the slopes of the FHH graphs of all samples are not uniform, so there is more than one fractal dimension. Based on previous studies 1, 26,38,39 , the nitrogen adsorption isotherm can be divided into two main regions with a relative pressure of 0.5 (P/P 0 = 0.5), obtaining two fractal dimensions, D1 and D2. Region 1 is the monolayer-multilayer adsorption in which the dominant force is van der Waals, and D1 can be calculated from the slope of the line in region 1. Region 2 is the capillary condensation regime, where the surface tension is the dominant force, and D2 can be calculated from the slope of the line in region 2 40,41 . D1 represents fractals from pore surface areas generated by surface irregularities, while D2 characterizes fractals related to pore structures that are controlled by the composition and pore parameters. Higher fractal dimension D1 correlates to more irregular surfaces that provide more space for CH 4 adsorption.
Higher fractal dimension D2 represents higher heterogeneity of pore structure and higher liquid/gas surface tension that reduce CH 4 adsorption capacity. The calculation results (Table 5) show obvious regularity. The D1 of the schist is lower than that of the mylonite; the average D1 of the schist is 2.1193, while the average D1 of the mylonite is 2.6782, indicating that the mylonite has more irregular surfaces.
The D2 of the schist is higher than that of the mylonite; the average D2 of the schist is 2.6643, while the average D2 of the mylonite is 2.4543, indicating that schist has a higher pore heterogeneity of pore structure. The mylonite has a higher D1 and lower D2, indicating that it has more natural gas reservoir space and stronger natural gas adsorption capacity, making it a better reservoir.

Formation process of the metamorphic rock reservoir
The U-Pb zircon dating results from our research team (  The concordant age of the the mica schist in Well LT1 is 275.2 ± 2.6 Ma, indicating that the diagenesis of its clastic protolith occurred no earlier than 275.2 Ma (early Permian). Because the upper granite formed in the middle-late Permian, the formation of the clastic rock should have occurred earlier than the middlelate Permian, so the formation time of the clastic rock can be constrained to the early-middle Permian. According to the structural background of the Songliao Basin and the four chronological test results, we hypothesize that the formation process of the metamorphic rock reservoir in the central paleo-uplift belt can be divided into the following four stages (Fig. 9): (1) Formation and weathering of Permian protoliths In the early-middle Permian, thick marine strata, i.e., the protoliths of the mica schist, were deposited ( Fig.   9-a), and granitic magma then intruded in the middle-late Permian to form granite, forming the protolith of the mylonite. From the end of the Permian to the Early Triassic, the collision of the northeastern block and the North China Craton occurred along the Sauron-Siramulun-Changchun suture zone; this process uplifted the crust, and the strata underwent erosion ( Fig. 9-b) 42 .
(2) Formation and weathering of Mesozoic protoliths Previous studies have found Triassic strata in the Songliao Basin 43 . The Middle Triassic strata began to be deposited, and the Late Jurassic granitic magma later intruded ( Fig. 9-c). In the Cretaceous period, when the Huoshiling Formation was deposited, during the low-angle subduction of the Paci c Plate towards the Asia-Europe Plate, basement faults became active 44 , and the Xuxi fault began to form ( Fig. 9d) 45 . During the Cretaceous Huoshiling-Shahezi depositional period, weathering and erosion occurred. During the late Shahezi-early Yingcheng depositional period in the Cretaceous, lava erupted to form andesite, representing the protolith of the chlorite schist ( Fig. 9-e). clastic rocks in the lower part were buried deeper, and the increase in temperature triggered regional metamorphism. The mud was transformed into biotite, muscovite, garnet and chlorite, and the feldspar and quartz particles became directionally aligned, forming the mica schist. From shallow to deep, the degree of ductile deformation gradually increased, and the deep rock layer experienced regional metamorphism, which conforms to the behavior of dynamic metamorphic rock (fault rock) 46 . The Late Jurassic granite was not metamorphosed because it was far from the fault ( Fig. 9-f).

(4) Weathering and deep burial
There is an unconformity between the Yingcheng Formation and Denglouku Formation in the Cretaceous, which is called the T4 unconformity surface. In the Yingcheng-Denglouku period, the strata underwent weathering and erosion. Because the Yingcheng Formation had a weak resistance to weathering and erosion, all of these rocks were removed. However, the chlorite schist is relatively resistant to weathering and erosion and was only partially removed, forming a weathering crust ( Fig. 9-g). Subsequently, the overlying Cretaceous Denglouku Formation was deposited ( Fig. 9-h). For granite (the protolith of the mylonite), dynamic metamorphism causes the originally dense granite to break and crack, having a constructive effect on the reservoir.
For clastic rocks (protoliths of the mica schist), regional metamorphism causes the minerals to recrystallize and directionally align, reducing the original pores and having destructive effects on the reservoir.
(3) Effect of structural location on microscopic pore characteristics The in uence of the structural position on microscopic pore characteristics is mainly re ected in the reservoir space derived from physical weathering. The chlorite schist and mylonite in the LT1 well and Late Jurassic granite in the LT2 well are weathered and eroded, so they all have weathering fractures, while the mica schist was below the surface, so no weathering fractures are observed.
(4) Effect of the protolith on microscopic pore characteristics Many microscopic pore characteristics are related to the protolith characteristics.
Andesite is formed by the eruption and rapid cooling of magma on the surface. Due to different volatiles, the vesicles in andesite are unevenly distributed, and phenocrysts are unevenly distributed in the matrix.
The rock can also undergo varying degrees of weathering and leaching at the surface. Therefore, andesite is not homogeneous. Clastic rocks are formed by cementing various types of debris with different grain sizes; thus, they are also not homogeneous. In contrast, granite forms underground where the temperature is higher. The temperature decreases slowly, and it takes a long time for granite to crystalize, so it is relatively homogeneous. Judging from the results, both HPMI and fractal algorithms reveal that the schist is more heterogeneous than the mylonite.
The protoliths of the schist, whether andesite or clastic rock, were loose and porous, while the protolith of the mylonite was granite, which is very dense and basically nonporous. The HPMI experiments show that the schist has a higher porosity than the mylonite, and the nitrogen adsorption tests show that the adsorption quantity and speci c pore volume of the schist are much higher than those of the mylonite. Although metamorphism reduced the pore space in the schist and increased the pore space in the granite, the original pore space of the protoliths largely controls the nal pore space.
Generally, among the three kinds of protoliths, argillaceous siltstone has the most clay minerals, andesite has the second highest amount, and granite has the lowest amount of clay minerals. According to the SEM observations, the mica schist has the most clay minerals, including biotite, montmorillonite and chlorite. The chlorite schist contains a large amount of chlorite, and the mylonite contains only a very small amount of chlorite.
Quartz and feldspar are both brittle granular minerals that are prone to cracking under tectonic stress 9 , while dark-colored minerals are more elastic, have high ductility and are not prone to cracking 10,15 . Therefore, microfractures have developed in the mylonite, but microfractures cannot be found in the schist.
In addition, the protoliths controlled the metamorphic histories of the rocks to some extent. The granite in the middle part and the clastic rocks in the lower part are continuous vertically, and both formed in the Permian, but their metamorphic styles are different. The clastic rocks contain many impurities, such as matrix material, mica and chlorite debris, which are prone to alteration. In contrast, the granite mineral composition is basically quartz and feldspar, which are simple, relatively stable and not prone to alteration. Temperature was the dominant factor in the metamorphism of the schist, which overall experienced regional metamorphism, while stress was the dominant factor in the metamorphism of the mylonite and caused partial dynamic metamorphism.
In summary, the microscopic pore characteristics of the metamorphic rock reservoir are controlled by the metamorphic style, structural location and protolith, among which the protolith was the most important controlling factor. Conclusions 1. Three metamorphic rock reservoir lithologies are revealed in wells LT1 and LT2: the chlorite schist formed by dynamic metamorphism from an andesitic protolith; the mylonite formed by dynamic metamorphism from a granitic protolith; and the mica schist formed by regional metamorphism from clastic protoliths.
2. The reservoir space can be divided into four types: intergranular pores, dissolved pores, structural microfractures and weathering microfractures.
3. The PSDs of the schist and mylonite are different.
4. Compared with the schist, the mylonite has less reservoir space, stronger homogeneity, larger pore size, smaller speci c surface area, more natural gas reservoir space and stronger natural gas adsorption capacity.
5. The formation process of the reservoir can be divided into four stages: formation and weathering of Permian protoliths, formation and weathering of Mesozoic protoliths, metamorphism and weathering and deep burial.
6. The microscopic pore characteristics of the metamorphic rock reservoir are controlled by the metamorphic style, structural location and protolith, among which the protolith is the most important controlling factor. Square concerning the legal status of any country, territory, city or area or of its authorities, or concerning the delimitation of its frontiers or boundaries. This map has been provided by the authors.