New UV Curable Acrylated Urethane-Oligoesters Derived From Poly(Ethylene Terephthalate) PET Waste

INTRODUCTION Polyethylene Terephthalate (PET) has been a well-known packaging material for many decades and is considered the world's top choice for many foods and beverages because of its hygienicity, high strength, light weight and shatterproofness. The highest application of PET lies in packaging carbonated soft drinks and water as a chemically safe material. The production of synthetic fibers from PET polymers fulfills more than half of the world’s demand. PET was first synthesized in the United States by the mid1940s when researchers were searching for an alternative synthetic material for natural textiles. Dacron is a branded synthetic polyester produced by DuPont. Furthermore, by the late 1950s, researchers managed to prepare stretched thin sheets of PET by extrusion molding to create films that are now extensively used as X-ray or photographic films. The technology of PET production and molding achieved much progress by the 1970s towards the formation of strong and lightweight bottles. PET is highly resistant to attack by microorganisms or reaction with food products, and this privilege places it on top of packaging materials used in the processing of foods, beverages, and pharmaceuticals. Based on these facts, health-safety agencies around the world have approved PET as safe for use with foods and beverages for many decades. The massive production of polymeric packaging materials around the world has implemented research work for their recycling to manage their increasing waste volume. PET is at the top of all recyclable polymer wastes due to its easy recycling and high sustainability, and it is the most recycled plastic in the United States and worldwide. PET is recycled into shorter chain oligomers and co-reacted with different raw reactant materials with various functional groups to produce new polymeric materials or reproduce PET back and used in forming containers for foods, beverages, pharmaceutical products, fibres for carpets and clothing, automotive parts and construction materials. Finding solutions to reduce the massive volume of discarded plastic products became mandatory for managing the growing portion of Municipal Solid Waste (MSW) (Liptak BG, 1991; Rhyner CR, et al., 2017). Statistical data revealed that the global production of PET increased from 41.56 million metric tons in 2014 to 73.39 million metric tons in 2020. Another instance of the high consumption of PET in the production of beverage bottles was recorded in 1987, where more than 700 million pounds were in this industry alone (Bledzki AK, 1997). The effective utilization of PET waste is considered of high economic and technological importance. PET can be depolymerized by different chemical methods, which is attributed to the relative chemical reactivity of its ester functional group, where its chemical reactivity is ranked among other carboxylic acid derivatives as follows: acid halides>acid anhydrides>esters>amides (Scheirs J and Long TE, 2005). The covalent bonding of the C atom to the more electronegative O atom from both ends in the ester linkage (O=C-O-) creates a permanent dipole with a positive charge (+) on the C atom and a negative charge (-) on the acyl O atom, and this polarity of the ester carbonyl group makes it highly reactive towards nucleophilic addition reactions. Nucleophilic reagents could be neutral or negatively charged. Examples of neutral nucleophiles are Lewis bases in their nature, such as amines, tively charged nucleophiles are anions such as cyanides, chlorides,


Introduction
Polyethylene terephthalate (PET) has been a well-known packaging material for many decades and is considered the world's top choice for many foods and beverages because of its hygienicity, high strength, light weight and shatterproofness. The highest application of PET lies in packaging carbonated soft drinks and water as a chemically safe material. The production of synthetic bers from PET polymers ful lls more than half of the world's demand. PET was rst synthesized in the United States by the mid-1940s when researchers were searching for an alternative synthetic material for natural textiles. Dacron is a branded synthetic polyester produced by DuPont. Furthermore, by the late 1950s, researchers managed to prepare stretched thin sheets of PET by extrusion molding to create lms that are now extensively used as X-ray or photographic lms. The technology of PET production and molding achieved much progress by the 1970s towards the formation of strong and lightweight bottles. PET is highly resistant to attack by microorganisms or reaction with food products, and this privilege places it on top of packaging materials used in the processing of foods, beverages, and pharmaceuticals. Based on these facts, health-safety agencies around the world have approved PET as safe for use with foods and beverages for many decades. The massive production of polymeric packaging materials around the world has implemented research work for their recycling to manage their increasing waste volume. PET is at the top of all recyclable polymer wastes due to its easy recycling and high sustainability, and it is the most recycled plastic in the United States and worldwide. PET is recycled into shorter chain oligomers and co-reacted with different raw reactant materials with various functional groups to produce new polymeric materials or reproduce PET back and used in forming containers for foods, beverages, pharmaceutical products, bres for carpets and clothing, automotive parts and construction materials. Finding solutions to reduce the massive volume of discarded plastic products became mandatory for managing the growing portion of municipal solid waste (MSW). 1,2 Statistical data revealed that the global production of PET increased from 41.56 million metric tons in 2014 to 73.39 million metric tons in 2020. Another instance of the high consumption of PET in the production of beverage bottles was recorded in 1987, where more than 700 million pounds were in this industry alone. 3 The effective utilization of PET waste is considered of high economic and technological importance. PET can be depolymerized by different chemical methods, which is attributed to the relative chemical reactivity of its ester functional group, where its chemical reactivity is ranked among other carboxylic acid derivatives as follows: acid halides > acid anhydrides > esters > amides. 4 The covalent bonding of the C atom to the more electronegative O atom from both ends PET waste can be depolymerized into shorter chain oligoesters by alcoholytic degradation as a Lewis base nucleophile. 5−11 PET can be depolymerized by other Lewis base nucleophiles, such as water (hydrolysis), amines (aminolysis), and glycols (glycolysis). Methanolysis has been evaluated as a method for recycling photographic and X-ray lms, with more than 158 x 10 6 kg converted since 1977. 12 However, large-scale degradation by methanolysis was not nancially e cient. 13 For the purpose of highly e cient methanolysis, high-pressure reactors should be involved in the process. 14

Results And Discussion
This work is a continuation of our previously published series of work 27-30 on the modi cation of oligoester polyols derived from the glycolysis reaction of PET waste. In our previous work, PET waste was depolymerized at different molar ratios of PET:DEG, and the obtained oligoester polyols were modi ed to acrylated and methacrylated UV curable oligomers 29,30 . In this work, the obtained oligoester polyols were reacted rst with half equivalents of TDI to insert a urethane moiety into the backbone of the polymer chain followed by modi cation of the terminal hydroxyl groups to acrylates. The purpose of incorporating the urethane nucleus into the polymer structure was to improve the mechanical characteristics of the nal cured lms. Figure 1 shows all the steps of glycolysis of PET and chemical reaction with TDI and modi cation with ACl to obtain the modi ed acrylated urethane-oligoester GLYUA. hydroxyl groups of GLYU were modi ed into acrylate groups through acrylation reaction 33,34 to prepare the modi ed product of acrylated urethane-oligoester GLYUA, which was copolymerized with different comonomers and tested for their mechanical properties. GLYUA was copolymerized with different UV curable comonomers, such as diethylene glycol diacrylate DEGDA, diethylene glycol dimethacrylate DEGDMA, triethylene glycol dimethacrylate TEGDMA and styrene Sty. Copolymerization and crosslinking reactions were carried out under UV irradiation using 2-benzyl-2-dimethylamino-1-(4-morphlinophenyl)-1butanone BDMB as a photoinitiator, and cured products were tested for their mechanical properties.

Molecular Weight Determination by End Group Analysis EGA
The number average molecular weights < M n > of the obtained GLY were calculated according to the end group analysis method by determination of the acid number (A) and hydroxyl value (B) (mg KOH/g sample) 35

Molecular Weight Determination by Gel Permeation Chromatography (GPC)
GPC analyses were performed on SEC Inst., using THF as a solvent at ambient temperature. For measurement, a 20 µL sample was injected at a ow rate of 1 mL/min. using waters 5/5 HPLC pump.
Two successive columns (PSS SDV linear XL 5 µ, 8x600 mm) and (PSS SDV 100 °Α 5 µ, 8x600 mm) were applied. Detection was performed on a Waters 410 Differential Refractometer using a linear UVIS-205 absorbance detector. We have investigated the structure of the obtained GLY under the same chemical conditions in our previous work 27 − 30, and it was shown that GLY contains (n = 3) hydroxyl groups per oligomer molecule, and the measured < M n > from EGA and GPC lies between 480-500 (g/mole).

Synthesis of Urethane-Oligoesters
Based on the measured hydroxyl value (B) by EGA, GLY was reacted with an equivalent of TDI to form urethane-oligoester GLYU with half equivalent of its terminal hydroxyl groups available for modi cation into acrylate terminal groups. Reaction with TDI was carried out by heating at 70°C in a vacuum oven for 12 hours to ensure complete reaction of cyanate groups with equivalent hydroxyl groups.

Synthesis of the Urethane-Ester Acrylated Oligomer
The terminal hydroxyl groups of the urethane-oligoester GLYU were modi ed to acrylate groups by reaction with acryloyl chloride according to a published procedure 33,34 . A 250 mL round-bottom threenecked ask equipped with a magnetic stirrer and a nitrogen sparge tube was charged with 150 mL tetrahydrofuran (THF), x mol of puri ed GLYU and 3x mol triethylamine. After cooling the mixture under a nitrogen spurge to 0 °C with an ice bath, the calculated equivalent moles of acryloyl chloride were added dropwise via an additional funnel over a 30 min time span. The mixture was kept at 0 °C for 3 h and allowed to reach room temperature and remain for an additional 3 h. After ltration and removal of the THF under vacuum, the crude product was dissolved in DCM. The obtained DCM solution was washed out with 1.0 M aqueous NaOH and saturated aqueous NaCl, three times in each case, followed by drying the organic layer over anhydrous Na 2 SO 4 . The nal solution was concentrated and puri ed by passage over an anhydrous silica column using a CH3OH/CH2Cl2 (50:50 v/v) mixture as a mobile phase. 41,42 The urethane-ester acrylated oligomer GLYUA was then copolymerized with UV curing with other comonomers and tested for Young's modulus, % elongation and break strength.

UV Curing
The nally synthesized and puri ed acrylated urethane-oligoester GLYUA was then cured solely under UV irradiation and as a comonomer with other UV curable monomers or a mixture of monomers. Curing was carried out by the addition of 2 wt.-% BDMB and UV irradiation at λ = 254 nm at an output intensity of 400 W/inch. The speed of the conveyor belt was 5 ft/min for a traveled distance of l = 33.0 inches. Cured lms were obtained by casting liquid mixtures of monomers onto glass plates for a de nite thickness controlled by using a steel thickness guard.

Essence Of The Measured Mechanical Properties
The mechanical characteristics of the tested cured lms were recorded in terms of the stress/strain relationship. The measured values of Young's modulus for the UV-cured samples were between 1.5 and 2.6 GPa), which represents a good achievement when comparing samples PU1-PU4 with similar samples from our previous work that did not contain urethane moieties, which showed Young's modulus values of (0.9-1.6 GPa) 29,30 . PU1 is the control sample for comparing the effect of the comonomer ratio on the measured mechanical properties, and it was cured solely under UV irradiation. The values of Young's modulus and break strength for the control sample PU1 were the lowest, but its % elongation was the highest when compared with other samples, which indicates its highest exibility. Samples PU2-PU4 were copolymerized with other comonomers at a ratio of 50% by weight, which resulted in pronouncedly improved values of Young's modulus and break strength, but the % elongation dropped to lower values, indicating the imparted stiffness to the samples. The sum of 50% by weight ratio of the comonomer was varied to include 25% by weight of styrene monomer to incorporate the polystyrene segments into the nal crosslinked structure of samples PU2-2, PU3-2 and PU4-2 and this did not change much of the values of Young's modulus but led to improvement in the break strength (MPa). The prevailing data in Table 1 indicated the success of our endeavor of incorporating a urethane moiety into the chemical structure of the glycolyzed product of PET waste. Second, copolymerization with other UV curable monomers helped drop the viscosity of the comonomer mixture, which made it more applicable in making cured lms and further improved the mechanical characteristics of Young's modulus (GPa) and break strength (MPa) to much higher values than the control sample. Styrene was incorporated as a comonomer because its segments are glassy and rigid, which should improve the mechanical strength and was established as indicated by the measured value of break strength.

Conclusion
Chemical degradation of PET waste by glycolysis reaction into polyol oligoesters is an interesting endeavor for creating new and innovative value-added products. Steps of modi cation of these polyol oligoesters were achieved by inserting urethane blocks into the chemical structure of the glycolyzed products in addition to modifying the terminal hydroxyl groups into UV curable acrylate moieties GLYUA. The mechanical properties of GLYUA cured solely with UV light were noticeably improved by copolymerization with 50% DEGDA, DEGDMA and TEGDA. The mechanical properties were further improved to the highest values by incorporation of 25% styrene monomer by weight.