1 Kulprathipanja, S. Zeolites in industrial separation and catalysis. 1-26 (John Wiley & Sons, 2010).
2 Sartbaeva, A., Wells, S. A., Treacy, M. & Thorpe, M. The flexibility window in zeolites. Nat. Mater. 5, 962-965 (2006).
3 Bolton, A. & Lanewala, M. A mechanism for the isomerization of the hexanes using zeolite catalysts. J. Catal. 18, 1-11 (1970).
4 Barthomeuf, D., Derouane, E. G. & Hölderich, W. Guidelines for mastering the properties of molecular sieves: relationship between the physicochemical properties of zeolitic systems and their low dimensionality. Vol. 221 (Springer Science & Business Media, 2013).
5 Kalantzopoulos, G. N. et al. Factors Determining Microporous Material Stability in Water: The Curious Case of SAPO-37. Chem. Mater. 32, 1495-1505 (2020).
6 Kapko, V., Dawson, C., Treacy, M. & Thorpe, M. Flexibility of ideal zeolite frameworks. Phys. Chem. Chem. Phys. 12, 8531-8541 (2010).
7 Tian, P., Wei, Y., Ye, M. & Liu, Z. Methanol to Olefins (MTO): From Fundamentals to Commercialization. ACS Catal. 5, 1922-1938, doi:10.1021/acscatal.5b00007 (2015).
8 Haw, J. F., Song, W., Marcus, D. M. & Nicholas, J. B. The Mechanism of Methanol to Hydrocarbon Catalysis. Acc. Chem. Res. 36, 317-326, doi:10.1021/ar020006o (2003).
9 Sastre, G., Lewis, D. W. & Catlow, C. R. A. Structure and stability of silica species in SAPO molecular sieves. J. Phys. Chem. 100, 6722-6730 (1996).
10 Silverwood, I. P. SAPO‐34 Framework Contraction on Adsorption of Ammonia: A Neutron Scattering Study. ChemPhysChem 20, 1747-1751 (2019).
11 Heard, C. J. et al. Fast room temperature lability of aluminosilicate zeolites. Nat. Commun. 10, 1-7 (2019).
12 Pugh, S. M., Wright, P. A., Law, D. J., Thompson, N. & Ashbrook, S. E. Facile, Room-Temperature 17O Enrichment of Zeolite Frameworks Revealed by Solid-State NMR Spectroscopy. J. Am. Chem. Soc. 142, 900-906 (2019).
13 Sun, T. et al. Water‐Induced Structural Dynamic Process in Molecular Sieve under Mild Hydrothermal Conditions: A Novel Ship‐in‐Bottle Strategy for Acidity Identification and Catalyst Modification. Angew. Chem. Int. Ed. Engl. 59, 2-12 (2020).
14 Stephan, D. W. The broadening reach of frustrated Lewis pair chemistry. Science 354, aaf7229 (2016).
15 Hounjet, L. J., Caputo, C. B. & Stephan, D. W. Phosphorus as a Lewis acid: CO2 sequestration with amidophosphoranes. Angewandte Chemie International Edition 51, 4714-4717 (2012).
16 Stephan, D. W. & Erker, G. Frustrated Lewis pair chemistry: development and perspectives. Angew. Chem. Int. Ed. Engl. 54, 6400-6441 (2015).
17 Hunger, M. Multinuclear solid-state NMR studies of acidic and non-acidic hydroxyl protons in zeolites. Solid State Nucl. Magn. Reson. 6, 1-29, doi:10.1016/0926-2040(95)01201-x (1996).
18 Zheng, A., Liu, S.-B. & Deng, F. P-31 NMR Chemical Shifts of Phosphorus Probes as Reliable and Practical Acidity Scales for Solid and Liquid Catalysts. Chem. Rev. 117, 12475-12531, doi:10.1021/acs.chemrev.7b00289 (2017).
19 Muller, M., Harvey, G. & Prins, R. Quantitative multinuclear MAS NMR studies of zeolites. Micropor. Mesopor. Mat. 34, 281-290, doi:10.1016/s1387-1811(99)00180-8 (2000).
20 Buchholz, A., Wang, W., Xu, M., Arnold, A. & Hunger, M. Thermal stability and dehydroxylation of Bronsted acid sites in silicoaluminophosphates H-SAPO-11, H-SAPO-81 H-SAPO-31, and H-SAPO-34 investigated by multi-nuclear solid-state NMR spectroscopy. Micropor. Mesopor. Mat. 56, 267-278, doi:10.1016/s1387-1811(02)00491-2 (2002).
21 Zhao, P. et al. Entrapped single tungstate site in zeolite for cooperative catalysis of olefin metathesis with Brønsted acid site. J. Am. Chem. Soc. 140, 6661-6667 (2018).
22 Martins, G. et al. Revisiting the nature of the acidity in chabazite-related silicoaluminophosphates: combined FTIR and 29Si MAS NMR study. J. Phys. Chem. C 111, 330-339 (2007).
23 Shen, W. et al. A study of the acidity of SAPO-34 by solid-state NMR spectroscopy. Micropor. Mesopor. Mat. 158, 19-25, doi:10.1016/j.micromeso.2012.03.013 (2012).
24 Wiper, P. V., Amelse, J. & Mafra, L. Multinuclear solid-state NMR characterization of the Brønsted/Lewis acid properties in the BP HAMS-1B (H-[B]-ZSM-5) borosilicate molecular sieve using adsorbed TMPO and TBPO probe molecules. J. Catal. 316, 240-250 (2014).
25 Schroeder, C. et al. Hydrogen Bond Formation of Brønsted Acid Sites in Zeolites. Chem. Mater. 32, 1564-1574 (2020).
26 Lo, B. T. et al. Elucidation of Adsorbate Structures and Interactions on Brønsted Acid Sites in H‐ZSM‐5 by Synchrotron X‐ray Powder Diffraction. Angew. Chem. Int. Ed. Engl. 128, 6085-6088 (2016).
27 Lo, B. et al. Dynamic modification of pore opening of SAPO-34 by adsorbed surface methoxy species during induction of catalytic methanol-to-olefins reactions. Appl. Catal. B 237, 245-250 (2018).
28 Zhao, P. et al. Structural dynamics of a metal–organic framework induced by CO 2 migration in its non-uniform porous structure. Nat. Commun. 10, 1-8 (2019).
29 Jeanvoine, Y., Ángyán, J. G., Kresse, G. & Hafner, J. Brønsted acid sites in HSAPO-34 and chabazite: an ab initio structural study. J. Phys. Chem. B 102, 5573-5580 (1998).
30 Li, G. et al. A nonpolar solvent effect by CH/interaction inside zeolites: characterization, mechanism and concept. Commun. Chem. 54, 13435-13438, doi:10.1039/c8cc08310j (2018).
31 Stephan, D. W. Frustrated Lewis pairs: from concept to catalysis. Acc. Chem. Res. 48, 306-316 (2015).
32 Wang, W. & Hunger, M. Reactivity of surface alkoxy species on acidic zeolite catalysts. Acc. Chem. Res. 41, 895-904 (2008).
33 Wang, C. et al. Extra‐Framework Aluminum‐Assisted Initial C− C Bond Formation in Methanol‐to‐Olefins Conversion on Zeolite H‐ZSM‐5. Angew. Chem. Int. Ed. Engl. 130, 10354-10358 (2018).
34 Zhu, Q. et al. The study of methanol-to-olefin over proton type aluminosilicate CHA zeolites. Micropor. Mesopor. Mat. 112, 153-161 (2008).
35 Goguen, P. W. et al. Pulse-quench catalytic reactor studies reveal a carbon-pool mechanism in methanol-to-gasoline chemistry on zeolite HZSM-5. J. Am. Chem. Soc. 120, 2650-2651, doi:10.1021/ja973920z (1998).
36 Zhao, X. B. et al. Investigation of methanol conversion over high-Si beta zeolites and the reaction mechanism of their high propene selectivity. Catal. Sci. Technol. 7, 5882-5892, doi:10.1039/c7cy01804e (2017).
37 Shah, R., Payne, M., Lee, M.-H. & Gale, J. D. Understanding the catalytic behavior of zeolites: A first-principles study of the adsorption of methanol. Science 271, 1395-1397 (1996).
38 Jiang, Y. J., Hunger, M. & Wang, W. On the reactivity of surface methoxy species in acidic zeolites. J. Am. Chem. Soc. 128, 11679-11692, doi:10.1021/ja061018y (2006).
39 Qian, Q. et al. Combined Operando UV/Vis/IR Spectroscopy Reveals the Role of Methoxy and Aromatic Species during the Methanol‐to‐Olefins Reaction over H‐SAPO‐34. ChemCatChem 6, 3396-3408 (2014).
40 Matam, S. K., Howe, R. F., Thetford, A. & Catlow, C. R. A. Room temperature methoxylation in zeolite H-ZSM-5: an operando DRIFTS/mass spectrometric study. Commun. Chem. 54, 12875-12878 (2018).
41 Matam, S. K., Nastase, S. A., Logsdail, A. J. & Catlow, C. R. A. Methanol loading dependent methoxylation in zeolite H-ZSM-5. Chem. Sci. 11, 6805-6814 (2020).
42 Kresse, G. & Furthmüller, J. Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set. Comput. Mater. Sci. 6, 15-50 (1996).
43 Kresse, G. & Furthmüller, J. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys. Rev. B 54, 11169 (1996).
44 Collignon, F., Jacobs, P. A., Grobet, P. & Poncelet, G. Investigation of the Coordination State of Aluminum in β Zeolites by X-ray Photoelectron Spectroscopy. J. Phys. Chem. B 105, 6812-6816, doi:10.1021/jp0106202 (2001).
45 van Bokhoven, J. A., van der Eerden, A. M. J. & Koningsberger, D. C. Three-Coordinate Aluminum in Zeolites Observed with In situ X-ray Absorption Near-Edge Spectroscopy at the Al K-Edge: Flexibility of Aluminum Coordinations in Zeolites. J. Am. Chem. Soc. 125, 7435-7442, doi:10.1021/ja0292905 (2003).
46 Brus, J. et al. Structure of Framework Aluminum Lewis Sites and Perturbed Aluminum Atoms in Zeolites as Determined by Al-27{H-1} REDOR (3Q) MAS NMR Spectroscopy and DFT/Molecular Mechanics. Angew. Chem. Int. Ed. Engl. 54, 541-545, doi:10.1002/anie.201409635 (2015).