Near cold subducting slab, the 410-km can be elevated due to the positive Clapeyron slope of the α-β phase transition13. Inside the slab where temperatures are lower than 1000°C, the nucleation and growth mechanism of the α-β phase transformation14 involving temperature-dependent atomic diffusion may be inhibited15. New pathways in the form of shear transformation mechanisms have been supported by the recent discovery of a new shear-induced high-pressure olivine polymorph, the ω-olivine phase (also known as ε*-phase), in heavily-shocked meteorites7-12. If this new diffusionless process occurs in Earth’s mantle, it will cause the seismic wave speed in the cold slab to decrease, associated with a grain size reduction.
Such a scenario could delay the arrival times of seismic waves that propagate a long distance through the slab in the vicinity of the α-β phase transition. In this paper, we analyze P waves generated by October 10, 2009, Mw 5.9 Kuril earthquake, which occurred at a depth of 114 km and was recorded by seismic stations in northeastern China. The position of the Kuril earthquake with respect to the seismic stations is ideal for studying the structure of the Pacific slab near the 410-km because P waves propagate hundreds of kilometers above or through the slab as illustrated by the Wadati-Benioff zone16 (Fig. 1a) and by the high-resolution FWEA1817 image of the mantle beneath the northwestern Pacific (Fig. 1b and 1c). In addition, the seismic stations are at epicentral distances between 1700 and 2400 km and record the triplication of P waves. The waveforms have up to three distinct pulses related to the direct wave that propagates above the 410-km and the upper interface of the slab and refracted waves that cross them. The 700-km long array aperture and the 50-km average station spacing allow us to link the traveltime and waveform characteristics of the P wave triplication to anomalous layering at a ~ 15-km scale corresponding to the width of the Fresnel zone.
We separate the seismic data into two subsets. The waveforms from stations along the source-receiver path RR’ are the reference data. Along RR’ the upper interface of the Pacific slab is located at about 450 km depth well below the 410-km. Since P waves along RR’ turn above the slab interface (Fig. 1b), we expect that the behavior of the P wave triplication can be explained by standard 1-D seismic velocity profiles of the mantle (Extended Data Fig. 1). In contrast, P waves recorded by stations along SS’ to the south of RR’ propagate several hundreds of kilometers through the high-velocity slab and are complicated by layering in the slab in the vicinity of the 410-km (Fig. 1c).
The onset times of the refracting P waves (Fig. 2a) provide the first clue that P waves along SS’ have decelerated by a low-velocity zone within the slab. First, the traveltime gradients indicate that the apparent velocities of the refracted waves are smaller for SS’ (i.e., 9.89 km/s) than for RR’ (i.e., 10.77 km/s) even though they have propagated within the high-velocity slab along SS’. Second, the travel times of the refracted waves along SS’ are similar or up to ~ 1 s longer than refracted waves along RR’ (Fig. 2a). For RR’, the refracted waves cross the 410-km discontinuity in the “normal” mantle (above the slab interface). However, for SS’, the refracted waves cross the 410-km discontinuity and propagate horizontally within the slab. Therefore, the similar travel times of the refracted waves point to a low-velocity zone inside the slab.
An alternative explanation for the delayed arrival time of the refracted waves along SS’ can be the lower velocities near the stations (e.g., at an epicentral distance of about 1500 km in Fig. 1c). Since such velocity anomaly will affect the direct waves and refracted waves to the same extent due to their almost identical ray paths at shallower depths (see the delayed arrival times for the direct waves along SS’ in Fig. 2a), the differential travel time between the refracting and direct P waves can cancel out such influence. The almost identical differential travel times between SS’ and RR’ (Fig. 2b) confirm our speculation of a low-velocity zone inside the slab.
By comparing recorded and computed waveforms of the P waves, we constrain the location, thickness, and velocity reduction of this low-velocity anomaly. We compute waveforms up to 0.5 Hz using the 2-D finite-difference method19 to avoid the high computational cost of 3-D solvers at 0.5 Hz. However, we acknowledge that complex 3-D wave propagation along the slab interface may cause some of the complexity in the P waveforms. We use the FWEA18 tomographic model of the mantle as a reference structure and perturb the layered wave-speed structure near the P-wave turning points (the region indicated by the box in Fig. 1c) to better explain the waveform. We argue that our quasi 1-D modeling of P-wave perturbations is justified given the 1-D character of the wave speed anomalies in FWEA18 near the P wave turning points, although more complex structures away from the turning points (e.g., near the source region) could contaminate the results (see Methods). We compare the synthetic and recorded waveforms after aligning each trace on the first arrival to isolate the influence of heterogeneity near the P wave turning points on the travel time differences and amplitudes of the direct and refracted waves. Waveforms are band-pass filtered between 0.02 and 1 Hz to minimize side-lobes. Since the waveforms with ray paths sub-parallel to the strike direction are very sensitive to the depths of the subducting slab, we further divided the stations along SS’ into sub-linear arrays S1S1’ and S2S2’ for source-station azimuth ranges of 262o-264o and 264o -266o, respectively.
There are two significant differences between the recorded and the synthetic P wave triplication computed for FWEA18 for the S1S1’ and S2S2’ profiles (Fig. 3a and 3b). For epicentral distances smaller than 1850 km, when the P waves propagate near the upper surface of the slab, the recorded P wave is weaker than the computed P wave because its energy is divided into two separate signals (see the waveforms for stations DNI, NE5E, NE4A along S1S1’ and station NE5D along S2S2’). Between 2000 and 2200 km, when the P waves propagate through the slab, the recorded P waveforms have three distinct peaks near about 46 s, 49 s, and 52 s. The FWEA18 synthetics match the first and the third peak (see for example stations HST, JCT, and LHTJ along S1S1’ and NE3A and PST along S2S2’) but do not predict the presence of the second peak due to the P-wave refraction through the slab’s upper surface. The waveform mismatch discrepancy at 0.5 Hz between the FWEA18 synthetics and the recorded waveforms is not surprising because the FWEA18 image is developed from waveforms with frequencies lower than 0.125 Hz (Extended Data Fig. 3) and has been parameterized to accommodate velocity variations over spatial scales larger than 50 km17. In contrast, along RR’ where seismic waves propagate in the ambient mantle (i.e., above the slab), the recorded waveforms are simpler with at most two peaks (Fig. 3c). The mismatches between the recorded data and the FWEA18 synthetics are mainly due to arrival time differences between the two peaks.
Our preferred seismic model, called “FWEA18-LVZ”, is a modification of FWEA18 in mainly two ways (see Fig. 4). First, the strength of the waveform anomaly in FWEA18 is tripled. This reduces the arrival time misfit and the stronger wave speed contrast across the slab’s upper interface predicts the double-peaked P waveform for the nearest stations (< 1850 km). The slab’s P-wave velocity anomaly of +6% in FWEA18-LVZ (increased from 2% in FWEA18) with respect to the ambient mantle is consistent with previous waveform modeling studies of the northeastern Pacific region20,21.
Second, a low-velocity layer centered at around 400 km depth (390 - 395 km along S1S1’ and 402 - 412 km along S2S2’) predicts the second of the three P-wave signals recorded between 2000 and 2200 km that is missing in the FWEA18 synthetics. The P-wave speed reduction must be at least 20%, with an apparent thickness of up to 16 km along the wave path (Fig. 4). The length of the low-velocity layer is fixed at 600 km, based on the length of the P wave segments through the slab along the S1S1’and S2S2’ profiles (see Fig. 1). The low-velocity layer decelerates the direct wave traveling through the slab and it extends the branch (cusp) of the triplication, generating a second pulse at ~ 49 s in the waveform (see Extended Data Fig. 4). Only a low-velocity layer (rather than a high-velocity discontinuity) can generate the missing second phase and predict the travel time difference of ~ 6 s between the first (at ~ 46 s) and the third (at ~ 52 s) pulses since the average wave speed in the slab is higher in FWEA18-LVZ than in FWEA18.
We explore the thickness and the velocity reduction of the low-velocity layer by a hybrid modeling approach. For each value of the velocity reduction from ~ 5% to 90% (with intervals of 5%), we determine the optimal thickness of the low-velocity zone and the vertical velocity structure (inside the box in Fig. 1c), via the Niching Genetic Algorithm22,23 (see Methods), to minimize the differences between recorded and synthetic waveforms. Fig 4 shows all the acceptable models that fit the recorded waveforms equally well. For instance, the match between the recorded and computed waveforms is similar for a low-velocity layer with either a thickness of 16 km and a velocity reduction of 20 % or a thickness of 2 km and a velocity reduction of 90%.
The nonuniqueness of the velocity reduction and the layer thickness is due to the minimum spatial resolution since the Fresnel zone of a P-wave (~ 0.5 Hz) is 15–20 km wide near the 410-km. This trade-off is evident in the acceptable models in the last iteration (Fig. 4), and also in the posterior distribution of all the 1,280 models (see Extended Data Fig. 5).
By experimentation, we find that the estimates of the thickness of the low-velocity layer and its velocity reduction depend slightly on the width of the low-velocity layer. However, minimum width of 200 km is necessary to produce the second P wave signal (Extended Data Fig. 6). The existence of such a low-velocity layer inside the slab is not only identified by the non-gradient-based modeling approach (with the Niching Genetic Algorithm22,23) but also confirmed by the sensitivity kernels derived from the adjoint method24 (Extended Data Fig. 7). Finally, our results do not have changed if we had chosen a different reference seismic structure (i.e., the 1-D IASP91 model instead of the FWEA18 model). Although the waveform fits are worse, a low-velocity layer centered at 370 km depth with a velocity reduction of 10–20% and a thickness of 20 km also explained the essential waveform features.
The velocity reduction is much stronger than the P-wave velocity contrast of 5% between the slab and the ambient mantle. Despite the trade-off between the layer thickness and the velocity reduction, the product of these two parameters is a constant (Extended Data Fig. 5). If we assume a velocity reduction of -5%, the low-velocity zone would be at least 50 km thick, implying that the lower half of the slab would be detached. Our waveform modeling also indicates that a -5% velocity reduction is not sufficiently strong to produce a second P wave signal. Therefore, we rule out the possibility that slab detachment could explain the low-velocity layer. Moreover, there is neither evidence for a gap in the Wadati-Benioff zone nor tomographic evidence that the Pacific slab would be weak and detached near the P-wave turning points, near 139o E longitude and 46o N latitude (see Fig. 1a). The presence of metastable olivine, whose P wave speed is 5% smaller than that of wadsleyite, is not a viable explanation either for the same reason.
Partial melting is inferred from the transition-zone water filter hypothesis25 and it is reasonable to consider it as a possible explanation for the wave speed anomaly observed above the 410-km, as usually done to interpret low-velocity layers in equilibrated mantle regions 26,27. However, there is no evidence for such a low velocity between 383 and 415 km depth for the reference source-receiver path RR’ where the slab is below the 410-km (Extended Data Fig. 1). It appears that the resolved low-velocity zone is confined to the Pacific slab. Thus, partial melting unlikely explains the velocity anomaly, as further confirmed by the fact that the location of the ultra-low-velocity layer along S1S1’ (383 to 402 km) is shallower than that along S2S2’ (395 to 415 km), correlating well with the relative depths of the Wadati-Benioff zone in these two regions (Fig. 1a).
Phase transformation, with volume reductions, is a mechanism for the reduction of the effective bulk modulus28,29. In zones (e.g, thickness of 5 – 30 km30-32 for the 410-km) where olivine (low-pressure phase) and wadsleyite (high-pressure phase) coexist, pressure perturbation by a passing seismic wave (e.g., on the order of ~ 10-7 GPa)33 will disrupt the equilibrium and induce the phase transformation. For a pyrolytic Earth model, the theoretical P-wave velocity reduction caused by the softening of the effective bulk modulus can be at most ~ 30%33,34, which falls well into our estimated value between 20% and 90%. However, such softening of the elastic modulus is unexpected in the cold slab, due to the slower kinetics35. We observe the ultra-low-velocity zone only inside the slab (along SS’) but not in the ambient mantle (along RR’) where softening is more likely.
Our preferred explanation of this ultra-low-velocity zone inside the slab is the existence of a layer of destabilized olivine which is associated with a significant grain size reduction: spineloid phase (β- and/or ω-olivine) would form as layers crosscutting the host olivine crystal, disorganizing the structure homogeneity and yielding a seismic wave speed reduction. In an experiment with ultrasonic interferometry and in situ X-ray diffraction, reduction of shear-wave velocity has been observed at the onset of the olivine-wadsleyite transformation and is interpreted as resulting from the existence of an intermediate spineloid phase (ω-olivine)36. We propose that such destabilized layer could consist of an intermediate phase transiently existing during the olivine–wadsleyite phase transformation within the cold subducting slab, where diffusion-assisted processes are inhibited. This intermediate phase, known either as ε*-phase or ω-olivine7-12, was at first theoretically predicted7, then observed in meteorites11,12. It was recently named poirierite12 and its transient (meta)stability could impact the rheology of the mantle36,37. Our seismological observations could highlight the transient (meta)stability of poirierite, under substantial shear stress, within the cold sinking slab. Nonetheless, any phase transformation at relatively low temperatures necessarily induces long-lived grain size reduction38,39, which is also known to reduce P-wave velocity40 and is expected to contribute to the observed reduction.
It is the first time an ultra-low-velocity zone (centered around 400 km, with a wave speed reduction of at least -20%) is identified inside a subducting slab. Viscosity reduction is usually associated with low-velocity zones41, which for instance would favor deformation and fragmentation of stagnant slabs in the mantle transition zone42-44. Further theoretical and experimental studies on grain size reduction caused by poirierite are needed to cross-check the value range we have provided in this study. And global-scale seismic studies are needed to provide more insights into olivine phase transitions in the deep Earth and planetary materials.