Ultrashort pulse laser structuring of hard materials prior to the grinding process significantly reduces the cutting forces and temperature and increases the achievable material removal rate of the grinding process. These effects are partially due to controllable induced damages into the subsurface of the structured workpieces. However, the impacts of this surface structuring technique on the material removal mechanism of advanced ceramics, such as Si3N4 are not yet thoroughly investigated. The dominant material removal mechanism in grinding hard and brittle materials such as silicon nitride (Si3N4), defines the surface integrity of the workpiece. For the first time, in-depth single diamond grit scratching experiments are carried out to investigate the changes in the dominant material removal mechanisms at various chip thicknesses by laser structuring of Si3N4. Two different structuring ratios (25% and 50%) were generated on sample surfaces by a femtosecond laser. The effects of laser structuring on material removal mechanism, pile-up area, area and width of the groove, grain path, normal and tangential forces, and specific cutting energy have been investigated. The results indicate that laser structuring considerably affects the reduction of depth ratio, normal (up to 89%) and tangential (up to 82%) forces, and specific cutting energy. The specific cutting energy of laser structured Si3N4 workpieces converged to about 5 J/mm3, much lower than that of unstructured workpieces.