Pump turbine operating conditions are complex, mainly including turbine mode and pump mode. Pump turbines have various instability problems during operation, such as S-shaped, pump hump, pressure pulsation and cavitation. PIV (Particle Image Velocimetry) is a very effective test technique for the internal flow field observation of pump turbines. In this paper, the internal flow field of pump hump, cavitation, pressure pulsation and four quadrants of the pump turbine are tested by PIV technology. The experimental observations show that the internal flow on those unstable working conditions of the pump turbine is extremely complicated. Those conditions which the vortex separation is serious and the flow angle is changed is far away the best efficiency working condition. Since the operating condition deviates from the optimal operating condition, the inflow Angle is changed and the inflow Angle is far away from the optimal inflow Angle.And the vortex induces and develops strongly by PIV test. The flow phenomenon are demonstrated at each operating points by PIV test.