This is a preprint, a preliminary version of a manuscript that has not completed peer review at a journal. Research Square does not conduct peer review prior to posting preprints. The posting of a preprint on this server should not be interpreted as an endorsement of its validity or suitability for dissemination as established information or for guiding clinical practice.
Research Article
W. Liu
Guangdong University of Technology
Corresponding Author
Shanghua Wu
Guangdong University of Technology
Corresponding Author
License:
This work is licensed under a CC BY 4.0 License. Read Full License
In this study, we combined liquid precursor infiltration of high introduction amounts of bi-additives (20wt%) and stereolithography-based 3D printing to fabricate zirconia toughened alumina, and the infiltration systems consist of the four following systems Zr4+/La3+, Zr4+/Er3+, Zr4+/Gd3+, and Zr4+/Ce4+. The sample immersed with Zr4+/La3+ shows intense peaks of m-ZrO2 phase compared to the other samples while a new phase of flake-like LaAl11O18 occurs in the Zr4+/La3+ immersed sample, the existence of which could be confirmed by XRD and EDS. The fracture toughness of the Zr4+/Er3+, Zr4+/Gd3+, and Zr4+/Ce4+ samples remained basically unchanged versus the crack size, while the measured fracture toughness values for the Zr4+/La3+ system could be fitted as a rising R-curve behavior with the steady-state fracture toughness of 17.76 MPa·m1/2. The enormous enhancement of the toughness could be attributed to thermal expansion misfit and flake-like LaAl11O18 in the Zr4+/La3+ system. The effect of residual stresses on the fracture mode and thus the toughness is discussed on the basis of theoretical calculation and analysis. It is the first time a rising R-curve behavior is observed in the 3D printed ceramics. The shocking discovery provides a highly effective toughening way in 3D printing combined infiltration approach.
Keywords
3D printing, Stereolithography, R-curve, Doping, Toughening
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This is a preprint, a preliminary version of a manuscript that has not completed peer review at a journal. Research Square does not conduct peer review prior to posting preprints. The posting of a preprint on this server should not be interpreted as an endorsement of its validity or suitability for dissemination as established information or for guiding clinical practice.
Research Article
W. Liu
Guangdong University of Technology
Corresponding Author
Shanghua Wu
Guangdong University of Technology
Corresponding Author
Badges
Prescreen
This manuscript passed our Prescreen assessment
Complete author information
Appropriate declaration statements
Potential risks to human health
Prescreen
History
CURRENT STATUS: Posted
Version 1
Posted 16 Apr, 2020
No community comments so far
Metrics
Comments: 0
PDF Downloads: ...
HTML Views: ...
Subject Areas
Ceramics
License:
This work is licensed under a CC BY 4.0 License. Read Full License
In this study, we combined liquid precursor infiltration of high introduction amounts of bi-additives (20wt%) and stereolithography-based 3D printing to fabricate zirconia toughened alumina, and the infiltration systems consist of the four following systems Zr4+/La3+, Zr4+/Er3+, Zr4+/Gd3+, and Zr4+/Ce4+. The sample immersed with Zr4+/La3+ shows intense peaks of m-ZrO2 phase compared to the other samples while a new phase of flake-like LaAl11O18 occurs in the Zr4+/La3+ immersed sample, the existence of which could be confirmed by XRD and EDS. The fracture toughness of the Zr4+/Er3+, Zr4+/Gd3+, and Zr4+/Ce4+ samples remained basically unchanged versus the crack size, while the measured fracture toughness values for the Zr4+/La3+ system could be fitted as a rising R-curve behavior with the steady-state fracture toughness of 17.76 MPa·m1/2. The enormous enhancement of the toughness could be attributed to thermal expansion misfit and flake-like LaAl11O18 in the Zr4+/La3+ system. The effect of residual stresses on the fracture mode and thus the toughness is discussed on the basis of theoretical calculation and analysis. It is the first time a rising R-curve behavior is observed in the 3D printed ceramics. The shocking discovery provides a highly effective toughening way in 3D printing combined infiltration approach.
Figure 1
Figure 2
Figure 3
Figure 4
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