This paper investigates the problem of parameter estimation for DC-DC buck converter without current sensors. For the circuit, all the parameters of capacitance, inductance, resistance and input voltage are unknown. A novel Volterra operator-based fixed-time adaptive algorithm is proposed by using only the output voltage and control input signals. By selecting proper kernel function for the Volterra integral operator, the influence of the system initial values can be eliminated and the calculation of the derivative of the system output can also be avoided. Strict analysis shows that the proposed estimation algorithm can ensure the estimation errors converge to zero in a fixed time independent of the initial error values. Finally, simulation results with different initial values verify the advantages of the proposed algorithm.