Urban solid waste (USW) is generated in residential homes, resulting from the disposal of materials used in domestic activities, the products consumed, and their containers, packaging, or wrapping. It also includes waste from any other activity within establishments or in public areas that produces waste with domestic characteristics, as well as those resulting from the cleaning of roads and public places, provided they are not considered by this Law as waste of another nature (Rohers et al. 2021).
In Mexico, 102,895.00 tons of waste are generated daily, of which 83.93% is collected and 78.54% is disposed of in final disposal sites (INEGI 2017). The primary management of USW continues to predominate, involving the collection and disposal of waste in landfills. Article 10 of the General Law for the Prevention and Comprehensive Management of Waste (LGPGIR) establishes that municipalities are responsible for the comprehensive management of urban solid waste, consisting of the collection, transfer, treatment, and final disposal (Gupta et al., 2014). Municipalities face various circumstances that, in many cases, are beyond their technical and financial capabilities due to the difficulty of having trained personnel. SEMARNAT promotes, through plans, programs, and the regulatory framework, that the management of urban solid waste is carried out under comprehensive management schemes, which include the prevention and reduction of its generation, its economic valorization, and its disposal in an adequate manner.
The generation of leachate from landfills today ranks among the most aggressive contaminants to the environment, mainly to the soil, and considering its characteristics and composition, it represents a potential risk for the contamination of surface and groundwater (Gao et al. 2021) (Table 1).
Standard NOM-083-SEMARNAT-2003 defines leachate as the liquid formed by the reaction, dragging, or filtration of the materials that constitute the waste and that contains, in dissolved or suspended form.
These substances can infiltrate the soil or runoff from the sites where waste is deposited, contaminating soil and bodies of water, causing deterioration, and representing a potential risk to human health and other living organisms. Leachates are often formed by combining large amounts of organic matter with different contaminants that can be toxic, therefore detailing significant impacts on the environment and not only on water bodies (Propp et al. 2021). Leachate in landfills contains diluted, suspended, fixed, or volatile substances, which causes them to have a high organic load (Cárdenas-Ferrer et al. 2020). The leachate contains high inorganic salts (sodium chloride and carbonate) and heavy metals (Jayawardhana et al. 2016; Kapelewska et al. 2016).
Table 1
Factors involved in the production of leachate.
Factors | Elements | Components |
Water infiltration | Rainfall Municipal solid waste coverage | -Geographic location -Time of year/weather aspects -Evaporation/Evapotranspiration -Waterproof thickness -Types of materials -Compaction -Pending |
Waste characteristics | Typology | -Composition -Humidity -Size and degree of compaction |
Microbial activities | Aerobic anaerobic activities | -Nature of the materials -Temperature -Carbon Nitrogen Relation -Hydrogen potential (pH) -Content of toxic substances |
Filling operation | Operational efficiency | -Temporary berms -Daily coverage of solid waste -Water deflection works |
Groundwater intrusion | Construction efficiencies | -Adequate waterproofing |
Lead in a Landfill originates from batteries, photographic waste, Lead-based paints, and Lead pipes. It is toxic to all forms of life at specific concentrations. Under acidic conditions, its release from litter can be promoted (De la Cruz et al. 2018; SWANA 1991). Lead is a toxic metal whose widespread use has caused environmental pollution and health problems in many parts of the world. It is a cumulative toxic substance that affects multiple body systems, including the cardiovascular and neurological systems hematological systems such as severe anemia, digestive system, and kidneys, and can also cause weakness in the fingers, wrists, or ankles. High exposure levels can seriously damage the brain and kidneys in adults or children and cause death (Chunying et al. 2021).
Nutrient pollution is one of the most widespread, costly, and complex environmental problems due to excess nitrogen and phosphorus in air and water. Although nitrogen and phosphorus are natural nutrients in aquatic ecosystems, air and water can become contaminated when they enter a system in large quantities, generally from various human activities. Nutrient pollution has affected many streams, rivers, lakes, bays, and coastal waters for several decades. Excess nitrogen in the air can affect our ability to breathe, reduce visibility, and disrupt plant growth (Koc-Jurczyk and Jurczyk 2020).
Excess nitrogen and phosphorus in leachate can lead to algal blooms called blooms and significantly reduce or eliminate the oxygen in the leachate. Some algal blooms harm humans, producing high amounts of toxins and bacterial growth. A person could get sick if they come into contact with contaminated water.
Nitrates (NO3) come from the dissolution of rocks and minerals, plant and animal matter decomposing, and industrial effluents. In wastewater, its presence is minimal, given the reduced state of this medium. The production and accumulation of NO3 in wastewater must be considered, as it becomes a limiting factor for growth in water systems if phosphorus is abundant, promoting undesirable phenomena such as eutrophication (Rapal 2010).
According to the NMX-AA-093-SCFI-2000 standard, electrolytic conductivity is a numerical expression of the ability of a solution to transport an electric current. This capacity depends on the presence of ions, their total concentration, mobility, valence and relative concentrations, and temperature. Determining conductivity is crucial because it explains the mineralization of natural, drinking, waste, treated waste, processed water, or water used in the laboratory for routine analysis or research work (Secretary of Economy 2000). The conductivity value is regulated by maximum permissible limits in wastewater discharges to the sewer or receiving bodies (Martínez-Cruz and Rojas-Valencia 2023).
It is also good to consider other factors, such as color and turbidity in the leachate, which are affected by its solid particles. The leachate generation process brings the dragging of much solid material (dissolved and in suspension), which leads to high values for these two parameters (Mendoza & Trujillo 2004).
Another parameter to measure in leachate is hardness, which is understood as the capacity of water to precipitate soap, and this is based on the presence of calcium and magnesium ions salts (Calabrò & Satira 2020). Hardness is responsible for forming scale in containers and pipes, which generates failures and losses of efficiency in different industrial processes such as heat transfer units. The term hardness was initially applied to represent difficult water to wash and refers to the consumption of soap for washing. Soap in most alkaline waters is directly related to the calcium and magnesium content (Peng 2017).
The final disposal and management of solid waste in landfills has become a constant problem for governments today. Increased rainfall for prolonged periods, combined with poor practices in collecting runoff water, causes increased leachate production at disposal sites (de Almeida et al. 2023; Fazzino et al. 2023). The generation of leachate from landfills today ranks among the most aggressive contaminants to the environment, mainly to the soil, and considering its characteristics and composition, it represents a potential risk for the contamination of surface and groundwater (Sumona et al. 2015).