(1) Bing, Y.; Liu, H.; Zhang, L.; Ghosh, D.; Zhang, J. Nanostructured Pt-Alloy Electrocatalysts for PEM Fuel Cell Oxygen Reduction Reaction. Chem. Soc. Rev. 39, 2184–2202 (2010).
(2) Debe, M. K. Electrocatalyst Approaches and Challenges for Automotive Fuel Cells. Nature 486, 43–51 (2012).
(3) Nibbelke, R. H.; Nievergeld, A. J. L.; Hoebink, J. H. B. J.; Marin, G. B. Development of a Transient Kinetic Model for the CO Oxidation by O2 over a Pt/Rh/CeO2/γ-Al2O3 Three-Way Catalyst. Appl. Catal. B Environ. 19, 245–259 (1998).
(4) Tanaka, H.; Taniguchi, M.; Uenishi, M.; Kajita, N.; Tan, I.; Nishihata, Y.; Mizuki, J.; Narita, K.; Kimura, M.; Kaneko, K. Self-Regenerating Rh- and Pt-Based Perovskite Catalysts for Automotive-Emissions Control. Angew. Chem. Int. Ed. 45, 5998–6002 (2006).
(5) Ding, K.; Gulec, A.; Johnson, A. M.; Schweitzer, N. M.; Stucky, G. D.; Marks, L. D.; Stair, P. C. Identification of Active Sites in CO Oxidation and Water-Gas Shift over Supported Pt Catalysts. Science 350, 189–192 (2015).
(6) Kuwahara, Y.; Yoshimura, Y.; Haematsu, K.; Yamashita, H. Mild Deoxygenation of Sulfoxides over Plasmonic Molybdenum Oxide Hybrid with Dramatic Activity Enhancement under Visible Light. J. Am. Chem. Soc. 140, 9203–9210 (2018).
(7) Chen, C. B.; Chen, M. Y.; Zada, B.; Ma, Y. J.; Yan, L.; Xu, Q.; Li, W. zhi; Guo, Q. X.; Fu, Y. Effective Conversion of Biomass-Derived Ethyl Levulinate into γ-Valerolactone over Commercial Zeolite Supported Pt Catalysts. RSC Adv. 6, 112477–112485 (2016).
(8) Siddiki, S. M. A. H.; Touchy, A. S.; Jamil, M. A. R.; Toyao, T.; Shimizu, K. I. C -Methylation of Alcohols, Ketones, and Indoles with Methanol Using Heterogeneous Platinum Catalysts. ACS Catal. 8, 3091–3103 (2018).
(9) Hartman, J. W., Hiscox, W. C. & Jennings, P. W. Catalytic Hydration of Alkynes with Platinum(II) Complexes. J. Org. Chem. 58, 7613–7614 (1993).
(10) Jiang, X. Bin, Minnaard, A. J., Feringa, B. L. & De Vries, J. G. Platinum-Catalyzed Selective Hydration of Hindered Nitriles and Nitriles with Acid- or Base-Sensitive Groups. J. Org. Chem. 69, 2327–2331 (2004).
(11) Lucey, D. W. & Atwood, J. D. Insight into the selective room-temperature platinum(II) catalytic hydration of alkynes in water. Organometallics 21, 2481–2490 (2002).
(12) Xing, X. et al. Highly Active Platinum Catalysts for Nitrile and Cyanohydrin Hydration: Catalyst Design and Ligand Screening via High-Throughput Techniques. J. Am. Chem. Soc. 140, 17782–17789 (2018).
(13) Scarso, A.; Colladon, M.; Sgarbossa, P.; Santo, C.; Michelin, R. A.; Strukul, G. Highly Active and Selective Platinum(II)-Catalyzed Isomerization of Allylbenzenes: Efficient Access to (E)-Anethole and Other Fragrances via Unusual Agostic Intermediates. Organometallics 29, 1487–1497 (2010).
(14) Bhanu Prasad, B. A., Yoshimoto, F. K. & Sarpong, R. Pt-catalyzed pentannulations from in situ generated metallo-carbenoids utilizing propargylic esters. J. Am. Chem. Soc. 127, 12468–12469 (2005).
(15) Pearson, R. G. Absolute Electronegativity and Absolute Hardness of Lewis Acids and Bases. J. Am. Chem. Soc. 107, 6801–6806 (1985).
(16) Dapsens, P. Y., Mondelli, C. & Pérez-Ramírez, J. Design of Lewis-acid centres in zeolitic matrices for the conversion of renewables. Chem. Soc. Rev. 44, 7025–7043 (2015).
(17) Li, Y., Li, L. & Yu, J. Applications of Zeolites in Sustainable Chemistry. Chem 3, 928–949 (2017).
(18) Corma, A.; González-Arellano, C.; Iglesias, M.; Navarro, M. T.; Sánchez, F. Synthesis of Bifunctional Au-Sn Organic-Inorganic Catalysts for Acid-Free Hydroamination Reactions. Chem. Commun. 46, 6218–6220 (2008).
(19) Corma, A.; Concepción, P.; Domínguez, I.; Forné, V.; Sabater, M. J. Gold Supported on a Biopolymer (Chitosan) Catalyzes the Regioselective Hydroamination of Alkynes. J. Catal. 251, 39–47 (2007).
(20) Sahoo, M.; Parida, K. Facile Fabrication of Organic-Inorganic Hybrid Material Based on Well-Dispersed AuNPs on Organo-Functionalised Zn-Al-Layered Double Hydroxides for Hydroamination of 1-Hexene. ChemistrySelect 3, 3092–3100 (2018).
(21) Lee, L. C.; Zhao, Y. Room Temperature Hydroamination of Alkynes Catalyzed by Gold Clusters in Interfacially Cross-Linked Reverse Micelles. ACS Catal. 4, 688–691 (2014).
(22) Gryparis, C.; Efe, C.; Raptis, C.; Lykakis, I. N.; Stratakis, M. Cyclization of 1,6-Enynes Catalyzed by Gold Nanoparticles Supported on TiO2: Significant Changes in Selectivity and Mechanism, as Compared to Homogeneous Au-Catalysis. Org. Lett. 14, 2956–2959 (2012).
(23) Ye, R.; Zhukhovitskiy, A. V.; Kazantsev, R. V.; Fakra, S. C.; Wickemeyer, B. B.; Toste, F. D.; Somorjai, G. A. Supported Au Nanoparticles with N-Heterocyclic Carbene Ligands as Active and Stable Heterogeneous Catalysts for Lactonization. J. Am. Chem. Soc. 140, 4144–4149 (2018).
(24) Stephan, D. W. Frustrated Lewis Pairs. J. Am. Chem. Soc. 137, 10018–10032 (2015).
(25) Cai, R.; Ye, X.; Sun, Q.; He, Q.; He, Y.; Ma, S.; Shi, X. Anchoring Triazole-Gold(I) Complex into Porous Organic Polymer to Boost the Stability and Reactivity of Gold(I) Catalyst. ACS Catal. 7, 1087–1092 (2017).
(26) Otake, K. I.; Ye, J.; Mandal, M.; Islamoglu, T.; Buru, C. T.; Hupp, J. T.; Delferro, M.; Truhlar, D. G.; Cramer, C. J.; Farha, O. K. Enhanced Activity of Heterogeneous Pd(II) Catalysts on Acid-Functionalized Metal-Organic Frameworks. ACS Catal. 9, 5383–5390 (2019).
(27) Tang, Z.; Liu, P.; Cao, H.; Bals, S.; Heeres, H. J.; Pescarmona, P. P. Pt/ZrO2 Prepared by Atomic Trapping: An Efficient Catalyst for the Conversion of Glycerol to Lactic Acid with Concomitant Transfer Hydrogenation of Cyclohexene. ACS Catal. 9, 9953–9963 (2019).
(28) Nie, L.; Mei, D.; Xiong, H.; Peng, B.; Ren, Z.; Hernandez, X. I. P.; DeLaRiva, A.; Wang, M.; Engelhard, M. H.; Kovarik, L.; et al. Activation of Surface Lattice Oxygen in Single-Atom Pt/CeO2 for Low-Temperature CO Oxidation. Science 358, 1419–1423 (2017).
(29) Daelman, N.; Capdevila-Cortada, M.; López, N. Dynamic Charge and Oxidation State of Pt/CeO2 Single-Atom Catalysts. Nat. Mater. 18, 1215–1221 (2019).
(30) Pereira-Hernández, X. I.; DeLaRiva, A.; Muravev, V.; Kunwar, D.; Xiong, H.; Sudduth, B.; Engelhard, M.; Kovarik, L.; Hensen, E. J. M.; Wang, Y.; et al. Tuning Pt-CeO2 Interactions by High-Temperature Vapor-Phase Synthesis for Improved Reducibility of Lattice Oxygen. Nat. Commun. 10, 1358 (2019).
(31) Dvořák, F.; Camellone, M. F.; Tovt, A.; Tran, N. D.; Negreiros, F. R.; Vorokhta, M.; Skála, T.; Matolínová, I.; Mysliveček, J.; Matolín, V.; et al. Creating Single-Atom Pt-Ceria Catalysts by Surface Step Decoration. Nat. Commun. 2016, 7. 10801.
(32) Li, X.; Jia, P.; Wang, T. Furfural: A Promising Platform Compound for Sustainable Production of C4 and C5 Chemicals. ACS Catal. 6, 7621–7640 (2016).
(33) Bouquillon, S.; Muzart, J. Palladium(0)-Catalyzed Isomerization of (Z)-1,4-Diacetoxy-2-Butene - Dependence of η1- or η3-Allylpalladium as a Key Intermediate on the Solvent Polarity. Eur. J. Org. Chem. 17, 3301–3305 (2001).
(34) Mukhopadhyay, M.; Reddy, M. M.; Maikap, G. C.; Iqbal, J. Cobalt(II)-Catalyzed Conversion of Allylic Alcohols/Acetates to Allylic Amides in the Presence of Nitriles. J. Org. Chem. 60, 2670–2676 (1995).
(35) Marion, N.; Gealageas, R.; Nolan, S. P. [(NHC)Au1]-Catalyzed Rearrangement of Allylic Acetates. Org. Lett. 9, 2653–2656 (2007).
(36) Zawisza, A. M.; Bouquillon, S.; Muzart, J. Palladium(II)-Catalyzed Isomerization of (Z)-1,4-Diacetoxy-2-Butene: Solvent Effects. Eur. J. Org. Chem. 2, 3901–3904 (2007).
(37) Ishida, T.; Honma, T.; Nakada, K.; Murayama, H.; Mamba, T.; Kume, K.; Izawa, Y.; Utsunomiya, M.; Tokunaga, M. Pd-Catalyzed Decarbonylation of Furfural: Elucidation of Support Effect on Pd Size and Catalytic Activity Using in-Situ XAFS. J. Catal. 374, 320–327 (2019).
(38) Datye, A. K.; Jones, J.; Pereira Hernandez, X. I.; Challa, S. R.; Pham, H.; Oh, S.; Qi, G.; Wiebenga, M. H.; Xiong, H.; DeLaRiva, A. T.; et al. Thermally Stable Single-Atom Platinum-on-Ceria Catalysts via Atom Trapping. Science 353, 150–154 (2016).
(39) Kunwar, D.; Zhou, S.; Delariva, A.; Peterson, E. J.; Xiong, H.; Pereira-Hernández, X. I.; Purdy, S. C.; Ter Veen, R.; Brongersma, H. H.; Miller, J. T.; et al. Stabilizing High Metal Loadings of Thermally Stable Platinum Single Atoms on an Industrial Catalyst Support. ACS Catal. 9, 3978–3990 (2019).
(40) Gracia, F. J.; Miller, J. T.; Kropf, A. J.; Wolf, E. E. Kinetics, FTIR, and Controlled Atmosphere EXAFS Study of the Effect of Chloride on Pt-Supported Catalysts during Oxidation Reactions. J. Catal. 209, 341–354 (2002).
(41) Ismagilov, Z. R.; Yashnik, S. A.; Startsev, A. N.; Boronin, A. I.; Stadnichenko, A. I.; Kriventsov, V. V.; Kasztelan, S.; Guillaume, D.; Makkee, M.; Moulijn, J. A. Deep Desulphurization of Diesel Fuels on Bifunctional Monolithic Nanostructured Pt-Zeolite Catalysts. Catal. Today 144, 235–250 (2009).
(42) Zhu, X.; Cheng, B.; Yu, J.; Ho, W. Halogen Poisoning Effect of Pt-TiO2 for Formaldehyde Catalytic Oxidation Performance at Room Temperature. Appl. Surf. Sci. 364, 808–814 (2016).
(43) Shi, H.; Gutiérrez, O. Y.; Yang, H.; Browning, N. D.; Haller, G. L.; Lercher, J. A. Catalytic Consequences of Particle Size and Chloride Promotion in the Ring-Opening of Cyclopentane on Pt/Al2O3. ACS Catal. 3, 328–338 (2013).
(44) Lee, J.; Ryou, Y.; Chan, X.; Kim, T. J.; Kim, D. H. How Pt Interacts with CeO2 under the Reducing and Oxidizing Environments at Elevated Temperature: The Origin of Improved Thermal Stability of Pt/CeO2 Compared to CeO2. J. Phys. Chem. C 120, 25870–25879 (2016).
(45) Bruix, A.; Rodriguez, J. A.; Ramírez, P. J.; Senanayake, S. D.; Evans, J.; Park, J. B.; Stacchiola, D.; Liu, P.; Hrbek, J.; Illas, F. A New Type of Strong Metal-Support Interaction and the Production of H2 through the Transformation of Water on Pt/CeO2(111) and Pt/CeOx/TiO2(110) Catalysts. J. Am. Chem. Soc. 134, 8968–8974 (2012).
(46) Brown, M.; Peierls, R. E.; Stern, E. A. White Lines in X-ray Absorption. Phys. Rev. B 15, 738–744 (1977).
(47) Bruix, A.; Lykhach, Y.; Matolínová, I.; Neitzel, A.; Skála, T.; Tsud, N.; Vorokhta, M.; Stetsovych, V.; Ševčíková, K.; Mysliveček, J.; et al. Maximum Noble-Metal Efficiency in Catalytic Materials: Atomically Dispersed Surface Platinum. Angew. Chem. Int. Ed. 53, 10525–10530 (2014).
(48) Lieske, H.; Lietz, G.; Spindler, H.; Völter, J. Reactions of Platinum in Oxygen- and Hydrogen-Treated Pt γ-Al2O3 catalysts. I. Temperature-Programmed Reduction, Adsorption, and Redispersion of Platinum. J. Catal. 81, 8–16 (1983).
(49) Gao, Y.; Wang, W.; Chang, S.; Huang, W. Morphology Effect of CeO2 Support in the Preparation, Metal-Support Interaction, and Catalytic Performance of Pt/CeO2 Catalysts. ChemCatChem 5, 3610–3620 (2013).
(50) Acerbi, N.; Tsang, S. C. E.; Jones, G.; Golunski, S.; Collier, P. Rationalization of Interactions in Precious Metal/Ceria Catalysts Using the d-Band Center Model. Angew. Chem. Int. Ed. 52, 7737–7741 (2013).
(51) Hu, Z.; Metiu, H. Halogen Adsorption on CeO2: The Role of Lewis Acid-Base Pairing. J. Phys. Chem. C 116, 6664–6671 (2012).
(52) Futatsugi, K.; Yamamoto, H. Oxazaborolidine-Derived Lewis Acid Assisted Lewis Acid as a Moisture-Tolerant Catalyst for Enantioselective Diels-Alder Reactions. Angew. Chem. Int. Ed. 44, 1484–1487 (2005).
(53) Honma, T.; Oji, H.; Hirayama, S.; Taniguchi, Y.; Ofuchi, H.; Takagaki, M. Full-Automatic XAFS Measurement System of the Engineering Science Research II Beamline BL14B2 at SPring-8. AIP Conf. Proc. 1234, 13–16 (2010).
(54) Oji, H.; Taniguchi, Y.; Hirayama, S.; Ofuchi, H.; Takagaki, M.; Honma, T. Automatic XAFS Measurement System Developed at BL14B2 in SPring-8. J. Synchrotron Radiat. 19, 54–59 (2012).
(55) Gaussian 09, Revision A.02, M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, G. Scalmani, V. Barone, G. A. Petersson, H. Nakatsuji, X. Li, M. Caricato, A. Marenich, J. Bloino, B. G. Janesko, R. Gomperts, B. Mennucci, H. P. Hratchian, J. V. Ortiz, A. F. Izmaylov, J. L. Sonnenberg, D. Williams-Young, F. Ding, F. Lipparini, F. Egidi, J. Goings, B. Peng, A. Petrone, T. Henderson, D. Ranasinghe, V. G. Zakrzewski, J. Gao, N. Rega, G. Zheng, W. Liang, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, T. Vreven, K. Throssell, J. A. Montgomery, Jr., J. E. Peralta, F. Ogliaro, M. Bearpark, J. J. Heyd, E. Brothers, K. N. Kudin, V. N. Staroverov, T. Keith, R. Kobayashi, J. Normand, K. Raghavachari, A. Rendell, J. C. Burant, S. S. Iyengar, J. Tomasi, M. Cossi, J. M. Millam, M. Klene, C. Adamo, R. Cammi, J. W. Ochterski, R. L. Martin, K. Morokuma, O. Farkas, J. B. Foresman, and D. J. Fox, Gaussian, Inc., Wallingford CT, 2016.
(56) Kresse, G.; Furthmüller, J. Efficient Iterative Schemes for Ab Initio Total-Energy Calculations Using a Plane-Wave Basis Set. Phys. Rev. B. 54, 11169–11186 (1996).
(57) Kresse, G.; Furthmüller, J. Efficiency of Ab-Initio Total Energy Calculations for Metals and Semiconductors Using a Plane-Wave Basis Set. Comput. Mater. Sci. 6, 15–50 (1996).
(58) Blöchl, P. E. Projector Augmented-Wave Method. Phys. Rev. B 50, 17953–17979 (1994).
(59) Perdew, J. P.; Burke, K.; Ernzerhof, M. Generalized Gradient Approximation Made Simple. Phys. Rev. Lett. 77, 3865–3868 (1996).
(60) McFarland, E. W.; Metiu, H. Catalysis by Doped Oxides. Chem. Rev. 113, 4391–4427 (2013).