This work studies the enhancement of the physical properties PVDF/PVC blend by adding ZnFe2O4 with different weight percent (from 0% up to 10%) as a nanofiller. The effect of ZnFe2O4 on behavior of PVDF/PVC was studied through XRD, FTIR, FESEM and UV-Visible spectroscopy. The PVDF/PVC/ 10% ZnFe2O4 nanocomposite film was represented the optimum sample. As it shows maximum crystallinity, roughness average (414 nm) and root mean square roughness (113nm) on another hand this sample has also the lowest value of energy band gap for direct and indirect transition. The removal efficiency of Cd(II) by using PVDF/PVC/ 10% ZnFe2O4 reached to about 50 % at pH 6 after 60min. the absorption mechanism as well as kinetics isotherm have been studied.