The main objective of the present study is to analyze the availability of solar photovoltaic system. The solar photovoltaic system in this paper is simple one consisting of four subsystems namely, solar panel subsystem, charge controller subsystem, batteries subsystem and inverter subsystem. Through the schematic diagram of state of the system, availability model is formulated and Chapmen - Kolmogorov differential equations are developed and solved using Gumbel Haugaard family Copula technique. The numerical values for availability, reliability, mean time to failure (MTTF), cost analysis as well as sensitivity analysis are presented. The effects of failure rates to various solar photovoltaic subsystems were developed.